Журнал "Макрогетероциклы"
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ISSN 1998-9539
Vol. 3 N 1
Preface |
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Biographic Review |
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 This biographic review is written on the occasion of the 100th Anniversary of Professor Vasilij Fedorovich Borodkin - one of the pioneer in the study of macroheterocyclic compounds in Soviet Union – and describes his scientific career and personal passions. |
E. A. Danilova,
M. K. Islyaikin
Vasiliy Fedorovich Borodkin – Pedagogue – Scientist – Personality
10 - 15
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Phthalocyanines |
Highlight |
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The organization of phthalocyanine-C60 fullerene conjugates is emerging as a powerful tool for the development of novel collective physical properties. This highlight presents the pioneering approaches on this topic.
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G. Bottari, T. Torres 16 - 18 |
Phthalocyanines |
Paper |
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Heterobimetallic µ-nitrido diphthalocyanine complex µ-(MnNFe)(tBuPc)2 was synthesized. This complex can be easily oxidized by dioxygen with formation of a stable green cation-radical with one unpaired electron.
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E. V. Kudrik, P. Afanasiev, A. B. Sorokin 19 - 22 |
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Paper describes synthesis of water-soluble mono- and disulfonaphthyloxy substituted phthalocynines and its complexes with cobalt and copper.
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V.P. Kulinich, G.P. Shaposhnikov, R. A. Badaukaite |
Phthalocyanines |
Сообщение |
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Direct synthesis of complexes of planar binuclear phthalocyanine sharing common annulated benzene ring providing the yields of the target products up to 40% was developed.
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A.Yu. Tolbin,
V.E. Pushkarev,
L.G. Tomilova, N.S. Zefirov New Approach to the Synthesis of Planar Binuclear Phthalocyanines of Mg, Zn and Rare Earth Elements 30 - 32
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Porphyrazinoids |
Microreview |
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Recent advances of authors in the chemistry of new representatives of macroheterocyclic compounds of ABAB-, ABBB- and ABABAB-types containing thiadiazole fragments are reviewed.
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E.A. Danilova,
T.V. Melenchuk,
O.N. Trukhina,
A.V. Zakharov, M.K. Islyaikin
Thiadiazole-Сontaining Macrocycles as Core-Modified Analogues of Phthalocyanine
33 - 37
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Porphyrazinoids |
Communication |
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New representatives of macroheterocyclic compounds of ABAB-type were synthezised by condensation of m-phenylenediamine or 2,6-diaminopyridine (A) with 5-tert-butyl-2,3-dicyanopyrazine (B) in n-butanol.
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M.G. Stryapan, S.V. Efimova, O.I. Koifman, M.K. Islyaikin |
Porphyrins |
Paper |
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Condensation of 2,3-octyl-1,4-dioxo-1,2,3,4-tetrahydro-6,7-phthalazinedicarboimide obtained from pyromellitic anhydride with phthalimide in the presence of zinc acetate leads to the formation of ZnII complex of tetrabenzoporphyrin with fused N‑octylmaleoimide fragment.
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N.E. Galanin, L.A. Yakubov, G.P. Shaposhnikov 41 - 47 |
Porphyrazines |
Communication |
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Аcylation of thiophenols with oxalylchloride leads to 2,3-thianaphthenequinones giving upon condensation with diaminomaleodinitrile the corresponding pyrazine-2,3-dicarbonitriles, which are easily cyclotetramerized upon melting to 2,3-thianaphthene-fused tetrapyrazinoporphyrazines.
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E.S. Taraymovich,
Yu.Yu. Enakieva,
Yu.V. Mitasova,
P.A. Stuzhin
Thianaphthene-Annulated Tetrapyrazinoporphyrazines
48 - 50
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Porphyrazines |
Paper |
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Joint experimental and theoretical study of spectral-luminescent properties and electronic structure of hexaphenylsubstituted and tribenzo-annulated 1,2,5-thiadiazolo- and 1,2,5-selenadiazoloporphyrazines has been performed.
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K.N. Solovyov, P.A. Stuzhin, V.A. Kuzmitsky, D.I. Volkovich, V.N. Knyukshto, E.A. Borisevich, A. Ul-Haque 51 - 62 |
Porphyrazines |
Paper |
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Five-coordinated MnIII complexes of tetraazaporphyrins and phthalocyanines containing trifluoromethyl- or tert-butyl-substituted aryl- or aryloxy- groups have been synthesized and characterized.
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E.N. Ovchenkova, M. Hanack, T.N. Lomova 63 - 67 |
N,S-Heterocycles |
Review |
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Syntheses and properties of 2,5-diamino-1,3,4-thiadiazole, 3,5-diamino-1,2,4-thiadiazole and 3-alkyl-5-amino-2-imino-1,3,4-thiadiazolines – building blocks for macroheterocyclic compounds are discussed in this review.
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E.A. Danilova, T.V. Melenchuk, O.N. Trukhina, M.K. Islyaikin 68-81 |
N,S-Heterocycles |
Paper |
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Simple and versatile synthetic methodologies have been elaborated for the novel 4-thiazolidinones and 5-arylidene derivatives of 2-methylimidazoles, which are perspective biologically important scaffolds for medicinal chemistry.
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R. Dua, S.K. Srivastava,
S.D. Srivastava Synthesis, Characterization and Antimicrobial Activity of 4-Oxothiazolidines and 5-Arylidene Derivatives of 2-Methylimidazoles 82 - 85 |
Crown Ethers |
Paper |
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Novel glycoluril-bridged bis(benzocrown ether)s have been synthesized and their complexation ability was examined in extraction of alkali metals picrates from water into chloroform.
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A.Yu. Lyapunov, V.N. Pastushok, T.I. Kirichenko, C.Yu. Kulygina, L.S. Kikot’, T.Yu. Bogaschenko, N.G. Luk’yanenko |
Conferences |
Notes |
 The survey of the Ist International Youth School-Conference on Physical Chemistry of Crown Compounds, Porphyrins and Phthalocyanines, which was held in the beginning of September 2009 in the Tuapse (Russia), is given. |
S.L. Selektor, A.Yu. Tsivadze |
Conferences |
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 The information is given on the VIIIth School-Conference of Young Scientists from the CIS states on Chemistry of Porphyrins and Related Compounds, which was held in Gagra (Abkhazia) 3-7 October 2009. |
O.A. Golubchikov, M.E. Klyueva 95 - 96 |
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