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ISSN 1998-9539

Vol. 3 N 1

Preface

 

Biographic Review

 
This biographic review is written on the occasion of the 100th Anniversary of Professor Vasilij Fedorovich Borodkin - one of the pioneer in the study of macroheterocyclic compounds in Soviet Union – and describes his scientific career and personal passions.
E. A. Danilova,
M. K. Islyaikin
Vasiliy Fedorovich Borodkin – Pedagogue – Scientist – Personality
10 - 15

Phthalocyanines

Highlight

The organization of phthalocyanine-C60 fullerene conjugates is emerging as a powerful tool for the development of novel collective physical properties. This highlight presents the pioneering approaches on this topic.

Abstract

G. Bottari, T. Torres
Towards Collective Physical Properties in Supramolecular Organized Phthalocyanine-C60 Fullerene Conjugates

16 - 18

Phthalocyanines

Paper

Heterobimetallic µ-nitrido diphthalocyanine complex µ-(MnNFe)(tBuPc)2 was synthesized. This complex can be easily oxidized by dioxygen with formation of a stable green cation-radical with one unpaired electron.

Abstract

E. V. Kudrik, P. Afanasiev, A. B. Sorokin
Synthesis and Properties of FeIII‑N=MnIV Heterometallic Complex with Tetra-tert-butylphthalocyanine Ligands

19 - 22

Phthalocyanines

Paper

Paper describes synthesis of water-soluble mono- and disulfonaphthyloxy substituted phthalocynines and its complexes with cobalt and copper.

Abstract

V.P. Kulinich,

G.P. Shaposhnikov, R. A. Badaukaite
Sulfonaphthyloxysubstituted Phthalonitriles and Phthalocyanines on their Basis
23 - 29

Phthalocyanines

Сообщение

Direct synthesis of complexes of planar binuclear phthalocyanine sharing common annulated benzene ring providing the yields of the target products up to 40% was developed.

Abstract

A.Yu. Tolbin,
V.E. Pushkarev,
L.G. Tomilova, N.S. Zefirov New Approach to the Synthesis of Planar Binuclear Phthalocyanines of Mg, Zn and Rare Earth Elements
30 - 32

Porphyrazinoids

Microreview

Recent advances of authors in the chemistry of new representatives of macroheterocyclic compounds of ABAB-, ABBB- and ABABAB-types containing thiadiazole fragments are reviewed.
E.A. Danilova,
T.V. Melenchuk,
O.N. Trukhina,
A.V. Zakharov, M.K. Islyaikin
Thiadiazole-Сontaining Macrocycles as Core-Modified Analogues of Phthalocyanine
33 - 37

Porphyrazinoids

Communication

New representatives of macroheterocyclic compounds of ABAB-type were synthezised by condensation of m-phenylenediamine or 2,6-diaminopyridine (A) with 5-tert-butyl-2,3-dicyanopyrazine (B) in n-butanol.

Abstract

M.G. Stryapan, S.V. Efimova, O.I. Koifman, M.K. Islyaikin
Synthesis and Properties of Macroheterocyclic Compounds of ABAB-type with tert-Butylpyrrole­pyrazine Fragments
38 - 40

Porphyrins

Paper

Condensation of 2,3-octyl-1,4-dioxo-1,2,3,4-tetrahydro-6,7-phthalazinedicar­boimide obtained from pyromellitic anhydride with phthalimide in the presence of zinc acetate leads to the formation of ZnII complex of tetrabenzoporphyrin with fused N‑octylmaleoimide fragment.

N.E. Galanin, L.A. Yakubov, G.P. Shaposhnikov
Synthesis and Properties of Tetrabenzoporphyrins with Fused N‑Octylmaleoimide Fragment

41 - 47

Porphyrazines

Communication

Аcylation of thiophenols with oxalylchloride leads to 2,3-thianaphthene­quinones giving upon condensation with diaminomaleodinitrile the corresponding pyrazine-2,3-dicarbonitriles, which are easily cyclotetramerized upon melting to 2,3-thianaphthene-fused tetrapyrazinoporphyrazines.

Abstract

E.S. Taraymovich,
Yu.Yu. Enakieva,
Yu.V. Mitasova,
P.A. Stuzhin
Thianaphthene-Annulated Tetrapyrazinoporphyrazines
48 - 50

Porphyrazines

Paper

Joint experimental and theoretical study of spectral-luminescent properties and electronic structure of hexaphenylsubstituted and tribenzo-annulated 1,2,5-thiadiazolo- and 1,2,5-selenadiazoloporphyrazines has been performed.

K.N. Solovyov, P.A. Stuzhin, V.A. Kuzmitsky,

D.I. Volkovich,

V.N. Knyukshto,

E.A. Borisevich, A. Ul-Haque
Porphyrazines with Annulated Chalco­gen-Containing Heterocycle: Study of Spectral-Luminescent Properties and Quantum-Chemical Calculations of the Excited Electronic States

51 - 62

Porphyrazines

Paper

Five-coordinated MnIII complexes of tetraazaporphyrins and phthalocyanines containing trifluoromethyl- or tert-butyl-substituted aryl- or aryloxy- groups have been synthesized and characterized.

Abstract

E.N. Ovchenkova,

M. Hanack, T.N. Lomova
Synthesis and Characterization of Some Five-Coordinated Tetraazaporphyrin and Phthalocyanine Manganese(III) Complexes

63 - 67

N,S-Heterocycles

Review

Syntheses and properties of 2,5-diamino-1,3,4-thiadiazole, 3,5-diamino-1,2,4-thiadiazole and 3-alkyl-5-amino-2-imino-1,3,4-thiadiazolines – building blocks for macroheterocyclic compounds are discussed in this review.

E.A. Danilova,

T.V. Melenchuk,

O.N. Trukhina,

M.K. Islyaikin
Diaminothiadiazoles - Building Blocks for Macroheterocycles

68-81

N,S-Heterocycles

Paper

Simple and versatile synthetic methodologies have been elaborated for the novel 4-thiazolidinones and 5-arylidene derivatives of 2-methylimidazoles, which are perspective biologically important scaffolds for medicinal chemistry.
R. Dua, S.K. Srivastava,
S.D. Srivastava
Synthesis, Characterization and Antimicrobial Activity of 4-Oxothiazolidines and 5-Arylidene Derivatives of 2-Methylimidazoles
82 - 85

Crown Ethers

Paper

Novel glycoluril-bridged bis(benzocrown ether)s have been synthesized and their complexation ability was examined in extraction of alkali metals picrates from water into chloroform.

Abstract

A.Yu. Lyapunov,

V.N. Pastushok,

T.I. Kirichenko,

C.Yu. Kulygina,

L.S. Kikot’,

T.Yu. Bogaschenko,

N.G. Luk’yanenko
Synthesis and Alkali Metal Picrate Extraction Capabilities of Novel Bis(benzocrown Ether)s Based on Diphenylglycoluril
86 - 92

Conferences

Notes

The survey of the Ist International Youth School-Conference on Physical Chemistry of Crown Compounds, Porphyrins and Phthalocyanines, which was held in the beginning of September 2009 in the Tuapse (Russia), is given.

S.L. Selektor,

A.Yu. Tsivadze
The Ist International Youth School-Conference on Physical Chemistry of Crown Compounds, Porphyrins and Phthalocyanines
93 - 94

Conferences

Notes

The information is given on the VIIIth School-Conference of Young Scientists from the CIS states on Chemistry of Porphyrins and Related Compounds, which was held in Gagra (Abkhazia) 3-7 October 2009.

O.A. Golubchikov,

M.E. Klyueva
The VIIIth School-Conference of Young Scientists from the CIS states on Chemistry of Porphyrins and Related Compounds (Gagra-2009)

95 - 96