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ISSN 1998-9539

Synthesis and Characterization of Some Five-Coordinated Tetraazaporphyrin and Phthalocyanine Manganese(III) Complexes

Ekaterina N. Ovchenkova,a Michael Hanack,b and Tatyana N. Lomovaa@


aInstitute of the Solution Chemistry of Russian Academy of Sciences, 153045 Ivanovo, Russia

bUniversität Tübingen, Institut für Organische Chemie, Morgenstelle 18, 72076 Tübingen, Germany


@Corresponding author E-mail:


DOI: 10.6060/mhc2010.1.63
Macroheterocycles 2010 3(1) 63-67


Soluble pentacoordinated manganese(III) complexes with substituted tetraazaporphyrins (TAPs) containing m-trifluoromethylphenyl, p-tert-butylphenyl groups and phthalocyanines (Pcs) containing m-trifluoromethylphenyl, m-trifluoromethylphenoxy and 3,5-di-tert-butylphenoxy groups have been synthesized either by direct metallation of macrocycles (TAPMn, 1a, and PcMns, 3a and 4a) or by template cyclotetramerization of the corresponding fumaronitrile (TAPMn, 2a) and phthalonitrile (PcMn, 5a) and characterized in details.


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