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New Approach to the Synthesis of Planar Binuclear Phthalocyanines of Mg, Zn and Rare Earth Elements

Alexander Yu. Tolbin,a,b Victor E. Pushkarev,b Larisa G. Tomilova,a,b@ and Nicolay S. Zefirova


aM.V. Lomonosov Moscow State University, Moscow, 119991, Russia

bInstitute of Physiologically Active Compounds, Russian Academy of Sciences, Chernogolovka, Moscow Region, 142432, Russia


@Corresponding author E-mail:


DOI: 10.6060/mhc2010.1.30
Macroheterocycles 2010 3(1) 30-32


Direct synthesis of planar binuclear phthalocyanine metallocomplexes sharing common annulated benzene ring providing the yields of target products up to 40%, in comparison with earlier described 5–11% yields, was developed. Generality of the elaborated method was shown by the example of synthesis of divalent (Mg, Zn) and rare-earth (Lu, Yb, Dy) metal complexes.


MHC2010_t03n01_30-32.pdf456.64 KB