Журнал "Макрогетероциклы"

 

 

The survey is given of the 10th International Conference on Physical and Coordination Chemistry of Porphyrins and Their Analogues (Ivanovo, July 1-4, 2009).

D. B. Berezin
10th International Conference on Physical and Coordination Chemistry of Porphyrins and Their Analogues (ICPC-10)
187-189

Works of authors on synthesis, study of structure and magnetic properties of molecular complexes formed by fullerene anions with metal porphyrins coordinated with one or two N-metyldiazabicyclooctane cations are reviewed.

D. V. Konarev, R. N. Lyubovskaya
Coordination structures of Metalloporphyrins with N-Containing Cations in Complexes with Fullerenes
190-197

A convenient and straightforward synthetic approach to tetrabenzo- and tetranaphtho¬porphyrins based on 4,7-dihydroisoindole and its benzoannelated derivative was developed.

M. A. Filatov, S. E. Aleshchenkov, A. V. Cheprakov
A Versatile General Approach to the Synthesis of Linearly Annelated π Extended Porphyrins via 4,7 Dihydroisoindole Derivatives
198-205

Self-assembly principles (based on the non-covalent two-fold extra-ligation) elaborated for the formation of porphyrin triads and pentads have been successfully employed to anchor tetrapyrrole molecules on semiconductor CdSe/ZnS quantum dot surfaces in solutions.

E. I. Zenkevich, C. von Borczyskowski
Photoinduced Relaxation Processes in Self-Assembled Nanostructures: Multiporphyrin Complexes and Composites “CdSe/ZnS Quantum Dot -Porphyrin”
206-220

Based on amino derivatives of 5,10,15,20-tetraphenylporphyrin and functionally substituted carboranes boronated porphyrins with high boron content (~30-35%) were obtained.

V. А. Ol’shevskaya, А. V. Zaitsev, Y. V. Dutikova,, V. N. Luzgina, E. G. Kononova, P. V. Petrovsky, V. N. Kalinin
A One Step Synthesis of Boronated meso-Tetraphenylporphyrins.
221-227

We described the synthesis of the series of mesogenic symmetrical 5,15- and 5,10,15,20-meso-arylsubstituted porphyrins containing long chain alkyl and acyl groups which exhibit thermotropic and lyotropic behaviour in nonpolar solvents, some of them being glassing mesogens.

N. A. Bragina, I. N. Fedulova, E. S. Krutikova, N. V. Novikov, A. F. Mironov, V. V. Bykova, N. V. Usol’tseva, G. A. Ananieva
Synthesis and Mesogenic Properties of Lipophilic and Amphiphilic Tetraphenylporphyrins
228-236

Radical polymerization of methyl metacrylate and styrene in the presence of iron and cobalt complexes of porphyrines have been studied and feasible polymerization scheme was proposed.

Yu. B. Monakov, R. M. Islamova, O. I. Koifman
Complexes of Iron and Cobalt Porphyrins for Controlled Radical
Polymerization of Methyl Metacrylate and Styrene
237-242

The reactions between the poly(methyl methacrylate) radical and the molecule of chloroiron(III) porphyrin complex have been studied using density functional theory approach.

A. K. Friesen
DFT Study of the Interaction between Chloroiron(III) Porphyrin and Poly(methylmethacrylate) Macroradical
243-245

Alkylation of 2,5-diamino-1,3,4-thiadiazole with alkylbromides leads to 3-alkyl-5-amino-2-imino-1,3,4-thiadiazolines which are condensed with 1,1-dimethoxy-3-iminoisoindoline with formation of new three-units products of ABA-type.

E. A. Danilova, T. V. Melenchuk, E. E. Melekhonova, M. A. Tyutina, M. K. Islyaikin
Three-unit Products from Condensation of 3-Alkylated 2,5-Diamino-1,3,4-thiadiazoles with 1,1-Dimethoxy-3-iminoisoindoline
246-250

Photophysical properties of the monodeprotonated form of 5,10,15,20-tetrakis(4-N-methylpyridiniumyl)porphyrin have been studied and it has been shown that intersystem crossing is the main pathway for the excitation energy deactivation.

M. M. Kruk, A. S. Starukhin
Excitation Energy Deactivation in Monodeprotonated Porphyrin
251-254

Planar and saddle-type distorted forms of the Pt-porphin were observed in solid matrices at liquid helium temperature and their optical properties have been studied.

A. S. Starukhin, M. M. Kruk
Fine Line Luminescence and Raman Spectra of Distorted Forms of Metalloporphyrins: Pt-porphin
255-257

The direct synthesis of monohydroxy substituted phthalocyanines has been developed with application of these compounds as building-blocks for selective preparation homo- and heteroligand bis-phthalocyanine complexes.

A. Yu. Tolbin, L. G. Tomilova
Application of Monohydroxyphthalo¬cyanines for Selective Preparation of Homo- and Heteroligand Macrocyclic Compounds
258-260

Monomeric derivative of Fe-phtalocyanine with trimethoxysilyl functional group was attached onto mesoporous molecular sieve SBA-15 and showed higher activity in liquid phase hydroxylation of phenol by hydrogen peroxide than ungrafted Pc analogue.

A. Yu. Tolbin, S. V. Sirotin, I. F. Moskovskaya, L. G. Tomilova, B. V. Romanovsky
Synthesis of Iron Phthalocyanine Grafted onto SBA-15 through Single Siloxane Bond and Its Application in Liquid-phase Hydroxylation of Phenol
261-263

Influence of different additives on kinetics of hydrogen peroxide decomposition catalyzed by hemin (FePP) and destruction of FePP was studied. Maximum of catalytic activity of FePP in hydrogen peroxide decomposition is shown to correspond to an associated form of FePP.

A.V. Lobanov, S.M. Vasiliev, G.G. Komissarov

Interaction of Hemin and Hydrogen Peroxide: Effect of Media
268-270

Geometric parameters of complexes formed by N,N,N,N-coordinating macroheterocyclic ligand 1,8-dioxa-3,6,10,13-tetraazacyclotetradecanetetrathione-4,5,11,12 with O=VIV, MnII, FeII, CoII, NiII, CuII and ZnII have been calculated using DFT B3LYP method with 6-31G(d) basic set

D. V. Chachkov, O. V. Mikhailov
DFT Calculations of Space Structures of MII Complexes with (N,N,N,N)-Coordinating Macroheterocyclic Ligand – 1,8-Dioxa-3,6,10,13-tetraaza¬cyclotetradecanetetrathione-4,5,11,12
271-274 

Pd-catalyzed amination of 3,3'-dibromobiphenyl with various polyamines and oxadiamines afforded a series of novel nitrogen- and oxygen-containing macroheterocycles in yields from moderate to good.

A. D. Averin, A. N. Uglov, A. K. Buryak, I. P. Beletskayaa
Facile Synthesis of New Polyazamacrocycles by the Pd-catalyzed Amination of 3,3'-Dibromobiphenyl
275-280

Pd-catalyzed amination of 1,3-dibromobenzene with N,N',N''-trimethylcyclam and N,N',N''-trimethylcyclen provided corresponding 1,3-bis(tetraazamacrocyclic) derivatives of benzene in 25-32% yields.

A. D. Averin, A. V. Shukhaev, A. K. Buryak, F. Denat, R. Guilard, I. P. Beletskayaa
Synthesis of 1,3-Bis(trimethylcyclam) and 1,3-Bis(trimethylcyclen) Substituted Benzenes
281-285

The synthesis and properties of the first representatives of fluorenonoazacrownophanes, bis(fluorenono)diazacrownophanes and fluorenonocryptand has been described.

A. V. Lobach, I. S. Yakovenko, N. G. Lukyanenko
Synthesis and Properties of the First Representatives of Fluorenonoazacrownophanes and Fluorenonocryptand

286-289

New fluorenocrownophanes containing fragments of 2,7-dioxyfluorene and hydroquinone or 4,4’-dioxybiphenyl linked by oligoethylene glycol residues were synthesized. The formation of the pseudorotaxane type inclusion complexes of these ligands with paraquat was established by means of FAB mass spectrometry, 1H NMR and electronic spectroscopy.

T. I. Kirichenko, A. V. Lobach, A. Yu. Lyapunov, C. Yu. Kulygina, I. S. Yakovenko, N. G. Lukyanenko
New Fluorenocrownophanes Containing Benzene or Biphenyl Fragments: Synthesis, Properties and Interaction with Paraquat
290-295