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ISSN 1998-9539

Coordination Structures of Metalloporphyrins with N-Containing Cations in Complexes with Fullerenes

Dmitri V. Konarev,@ and Rimma N. Lyubovskaya


Institute of Problems of Chemical Physics of Russian Academy of Sciences, Chernogolovka, Moscow region, 142432, Russia


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Ionic complexes of fullerenes with metalloporphyrins attract much attention due to promising photophysical and magnetic properties. We design these complexes using the coordination bonding between metalloporphyrins and N-containing cations (M-N(L+) bonds). In this review we discuss 1). C60•−, C602− and C70− complexes with (MDABCO+)2⋅MIITPP units (MDABCO+ is N-methyldiazabicyclooctane cation, M = Zn, Co, Mn, Fe, 1-6) having six-coordinated metal centres; 2). C60− complexes with (MDABCO+)⋅MIITMPP (M = Zn (7), Co (8)) and (MDABCO+)⋅MIIOEP units (M = Zn, Co, Mn, Fe, 9-12) having five-coordinated metal centres. We discuss synthesis of the complexes, structures of metalloporphyrins coordinatively bound with N-containing cations formed in the complexes with
fullerenes, and the magnetic properties of the complexes.

MHC2009_t02n03-04_190-197.pdf1.15 MB