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ISSN 1998-9539

Synthesis of Iron Phthalocyanine Grafted onto SBA-15 through Single Siloxane Bond and its Application in Liquid-Phase Hydroxylation of Phenol

Alexander Yu. Tolbin,a,b@ Sergey V. Sirotin,a Irina F. Moskovskaya,a Larisa G. Tomilova,a,b and Boris V. Romanovskya

aM.V. Lomonosov Moscow State University, Moscow, 119991, Russia

bInstitute of physiologically active compounds, Russian Academy of Sciences, Moscow Region, Chernogolovka, 142432, Russia

@Corresponding author E-mail:

Iron(III) phthalocyanine monosubstituted with trimethoxysilyl derivative was attached via covalent bonding onto SBA-15 support in order to obtain catalyst for activation of environmentally friendly oxidant – hydrogen peroxide. Catalyst prepared was tested in liquid-phase oxidation of phenol at 60°C. Covalently bonded complex exhibit higher activity than its unpendant analog.

MHC2009_t02n03-04_261-263.pdf457.86 KB