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ISSN 1998-9539

Vol.1 N.1

Preface

7-8

Porphyrinoids

Review

A review on the synthesis and metalation of carbaporphyrinoid systems is presented. These porphyrin analogues are superior organometallic ligands that are starting to rival the better known N-confused porphyrins

Abstract

T. D. Lash
 

Metalation of Carbaporphyrinoid Systems

 

9-20

Porphyrazines

Microreview

Review summarizes the recent knowledge about the syntheses, spectral properties, aggregation, protonation and deprotonation of macrocycle and singlet oxygen and fluorescence quantum yields of azaphthalocyanines bearing substituted pyrazine rings in their conjugated system.

Abstract 

P. Zimcik, V. Novakova, M. Miletin, K. Kopecky


Azaphthalocyanines Containing Pyrazine Rings with Focus on the Alkylheteroatom, Aryl and Heteroaryl Substitution and Properties Important in Photodynamic Therapy

 

21-29
 

Porphyrazines

Paper

Results of authors’ on the study of triazoleporphyrazines, structural analogues of porphyrazine containing one triazole ring instead of one of pyrrole subunits are summarized.

Abstract

M. K. Islyaikin, O. N. Trukhina, Y. V. Romanenko, E. A. Danilova, O. G. Khelevina
 

 

Synthesis, Structure Peculiarities and Acid-Basic Behaviour of Triazoleporphyrazines

 

30-39

Porphyrazines

Paper

Described in this report is the synthesis and optical spectroscopic characterization of two novel dipyrrolylquinoxaline analogues – triazolehemipyrazinoporphyrazines that are functionalized with four pyrrole rings.

Abstract 

M. S. Rodríguez-Morgade, G. D. Pantos, E. Caballero, J. L. Sessler, T. Torres

 

Synthesis of Hemipyrazinoporphyrazines Bearing Peripheral Pyrrolic Substituent

 

40-43

Phthalocyanines

Paper

 

Authors report on synthesis and spectral study of new double-decker phthalocyaninates of lutetium(III) and indium(III) with fourcalix[4]arene bridges

 

Abstract

T. Ceyhan, G. Yağlioğlu, H. Ünver, B. Salih, M. K. Erbil, A. Elmali, Ö. Bekaroğlu


Synthesis, Characterization and Optical Limiting Properties of Novel Ball-type Four tert-Butylcalix[4]arene Bridged Double-decker Lutetium(III) and Indium(III) Phthalocyanines

 

44-49
 

Porphyrins

Paper

 

The titration of the diprotonated form of 3,7,13,17-tetramethyl-2,8,12,18-tetrabutylporphyrin with the series of halide ions has been done in the acetonitrile solution and the influence of complexation with iodide ions on the porphyrin fluorescent properties has been studied.

Abstract 

 M. M. Kruk, Yu. B. Ivanova, V. B. Sheinin, A. S. Starukhin, N. Zh. Mamardashvili, O. I Koifman


Highly Sensitive Halide Ions Recognition with Diprotonated Porphyrin

 

50-58

Porphyrins

Paper

 

On the basis of laser confocal fluorescence microscopy, ensemble averaged steady-state and kinetic measurements it was shown that closely displaced aminophenyl substituted porphyrins in bright spots on polypropylene film surface do not form aggregates and possess monomeric emission.

 

Abstract 

E. I. Zenkevich, J. Martin, C. von Borczyskowski, T. A. Ageeva, V. A Titov, V. N. Knyukshto


Laser Confocal and Spatially-Resolved Fluorescence Spectroscopy of Porphyrin Distribution on Plasma Deposited Polymer Films

 

59-67

Porphyrins

Paper

Magnetocaloric effect and specific heat capacity of 6% MnIII octaethyl¬porphyrin suspension in water were measured by microcalorimetric method in the dependence of temperature (298-353 K) and magnetic field (0-0.7 T).

 


Abstract 

V. V. Korolev, M. E. Klyueva, I. M. Arefyev, A. G. Ramazanova, T. N. Lomova, A. G. Zakharov
 

 

Regularities of Magnetocaloric Effect and Determination of Some Thermo¬dynamic Parameters for (Octaethyl¬porphynato)chloromanganese(III)

 

68-71

Porphyrins

Paper

The reactions of metalloporphyrins formation are pH-dependent. Acid-basic properties of porphyrin ligands are changed in wide area and determined the mechanism of complex formation.

Abstract

V. B. Sheinin, O. R. Simonova, E. L. Ratkova

 

Effect of pH on Formation of Metalloporphyrins

 

72-78

Porphyrins

Communication

 

Unexpected electronic structures are unravelled by computational methods for recently-observed ferric-oxo states in hemoproteins.

Abstract

R. Silaghi-Dumitrescu
 

 

The Ferric-Oxo Moiety in Porphyrin Complexes – a Ferryl in Disguise?

 

79-81
 

Porphyrazines

Communication

Attempt to obtain imidazoporphyrazine by deselenation of 1,2,5-selenadiazoloporphyrazine and subsequent treatment of “diaminoporphyrazine” with formic acid unexpectedly led to diformamidoporphyrazine.

 


Abstract

A. Ul-Haq, P. A. Stuzhin
 

 

Conversion of 1,2,5-Selenadiazoloporphyrazine to Diformamidoporphyrazine

 

82-84

Crown-ethers

Paper

Halogenation of benzo- and dibenzocrown ethers with N-halogenosuccinimides in solid phase, water or organic medium was studied.

Abstract

 S. A. Kotlyar, S. M. Pluzhnik-Gladyr
 

 

The Peculiarities of the Reaction of Benzo- and Dibenzocrown Ethers with N-Halogenosuccinimides

 

85-89
 

Template synthesis

Paper

Template synthesis processes for the triple systems MII ion – ambidentate (N,S)-,(N,O,S)-synthon– (C=O)-synthon (M= Co, Ni, Cu) in the solutions and in gelatin-immobilized matrix were studied and analyzed.

Abstract 

O. V. Mikhailov, M. A. Kazymova, D. V. Chachkov
 

 

Template Synthesis into Gelatin-Immobilized Matrix as Perspective Method of Obtaining Supramolecular Macroheterocyclic Compounds

 

90-97

 

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