Redox Reactions of μ-Carbido Diiron(IV) Tetra-4-tert-butylphthalocyaninate with Organic Peroxides

Olga R. Simonova,^a^@ Svetlana V. Zaitseva,^a Sergey A. Zdanovich,^a and Oskar I. Koifman^a,b

^aKrestov Institute of Solution Chemistry, Russian Academy of Sciences, 153045 Ivanovo, Russia

^bIvanovo State University of Chemistry and Technology, 153000 Ivanovo, Russia

^@Corresponding author E-mail: ors@isc-ras.ru

DOI: 10.6060/mhc180173s

Macroheterocycles 2018 11(1) 29-34

The interaction of μ-carbido diiron(IV) tetra-4-tert-phthalocyaninate with tert-butylhydroperoxide and tert-butylperoxide was studied spectrophotometrically. The kinetic characteristics were obtained and a possible mechanism of redox interaction, influenced by the nature of the peroxide, was proposed. The reaction is redox multi-step process, where the coordination of peroxide molecule on the iron center with subsequent homolytic O-O bond cleavage follows after one-electron oxidation of the complex up to π-cation radical. The resulting π-cation radical species can be easily reduced in the presence of imidazole up to a neutral form. The catalytic activity of the oxidized species of the dimeric iron(IV) complex in the lycopene oxidation reaction is shown.

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Redox Reactions of μ-Carbido Diiron(IV) Tetra-4-tert-butylphthalocyaninate with Organic Peroxides

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