Complex Formation and Photochemical Properties of the Crown-Containing Mono- and Bis(styryl)bipyridine Derivatives with Transition Metal Cations

Nikolay E. Shepel,^a Olga A. Fedorova,^a Elena N. Gulakova,^a Gedeminas Jonusauskas,^b and Yuriy V. Fedorova^@

^aA.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, 119991 Moscow, Russia

^bCentre de Physique Moléculaire Optique et Hertzienne, U.M.R. 5798 UNIVERSITÉ BORDEAUX 1 – CNRS, 351, Cours de la Libération – 33405 TALENCE CEDEX, France

^@Corresponding author E-mail: fedorov@ineos.ac.ru

DOI: 10.6060/mhc2010.4.201
Macroheterocycles 2010 3(4) 201-209

Complex formation of 15-crown-5 ether containing mono- and bis(styryl)bipyridine with transition metal perchlorates was studied. The complex stoichiometry, complex structure and stability constants were determined by electronic spectroscopy. The influence of metal ions on occurrence of E,Z-isomerization was analyzed; the optical characteristics of two isomers were calculated from the photolysis data.

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