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ISSN 1998-9539

Liquid-Phase Hydrogenation of the Nickel Complex with Tetra(4-tert-butyl-5-nitro)phthalocyanine

Mikhail V. Klyuev,a@ Natalya A. Magdalinova,a Mariya E. Klyueva,b Tatiana V. Tikhomirova,c and Vladimir E. Maizlishc 
aIvanovo State University, 153025 Ivanovo, Russian Federation
bIvanovo State Medical Academy, 153012 Ivanovo, Russian Federation
cIvanovo State University of Chemistry and Technology, 153000 Ivanovo, Russian Federation
Corresponding author E-mail:
DOI: 10.6060/mhc211247k
Macroheterocycles 2021 14(3) 201-203
Dedicated to Professor Olga G. Khelevina on the occasion of her Anniversary
The liquid-phase hydrogenation of a nickel complex with tetra(4-tert-butyl-5-nitro)phthalocyanine was carried out in the presence of activated carbon containing palladium under mild conditions (the solvent was ethanol, Т = 318 K, Рн2 = 0.1 MPa). It has been shown that during hydrogenation, all the nitro groups of the substrate are simultaneously reduced, while the reduction of other bonds does not occur. The structure of the reduction product, nickel complex with tetra(4-tert-butyl-5-amino)phthalocyanine, was confirmed by UV-vis and mass spectroscopy data.


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