Benzoannelated A3B-Phthalocyanines with Diethyleneglycol Substituents: Synthesis and Control of Aggregation

Alexey V. Yagodin,^a Alexander G. Martynov,^a^@ Yulia G. Gorbunova,^a,b and Aslan Yu. Tsivadze^a,b

^aA.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071 Moscow, Russia

^bN.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russia

^@Corresponding author E-mail: Martynov.Alexandre@gmail.com

DOI: 10.6060/mhc210541m

Macroheterocycles 2021 14(2) 130-134

New benzoannelated phthalocyanine H₂A₃B has been synthesized by cross-condensation of 4,5-dibutoxyphthalonitrile A and naphthalonitrile B bearing two diethyleneglycol substituents. UV-Vis and ¹H NMR measurements performed for H₂A₃B showed that the presence of free OH-groups in H₂A₃B enhances its aggregation in solution in comparison with its O-tetrahydropyranyl derivative H₂A₃Bt, which can be considered as a way to control the physicochemical properties of asymmetric phthalocyanines.

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Benzoannelated A3B-Phthalocyanines with Diethyleneglycol Substituents: Synthesis and Control of Aggregation

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