Revisiting the One-Step Synthesis of Heteroleptic Lanthanide(III) (Porphyrinato)(Phthalocyaninates): Opportunities and Limitations

Kirill P. Birin,^a@ Anna I. Poddubnaya,^b Yulia G. Gorbunova,^a,c and Aslan Yu. Tsivadze^a,c

^aA.N. Frumkin Institute of Physical Chemistry and Electrochemistry RAS, 119071 Moscow, Russia

^bD.I. Mendeleev University of Chemical Technology of Russia, 125047 Moscow, Russia

^cN.S. Kurnakov Institute of General and Inorganic Chemistry RAS, 119991 Moscow, Russia

^@Corresponding author E-mail: kirill.birin@gmail.com

DOI: 10.6060/mhc171258b

Macroheterocycles 2017 10(4-5) 514-519

The influence of the porphyrin and phthalocyanine ligand nature onto the yield and selectivity in the one-step synthesis of heteroleptic triple-decker early lanthanide (porphyrinato)(phthalocyaninates) is investigated with 6 porphyrins, 4 phthalocyanines and 2 lanthanides as examples. It is found that the presence of electron-donating substituents in the phthalocyanine macrocycle allows efficient one-step formation of symmetrical triple-decker complexes of [Por]Ln[Pc]Ln[Por] type. In contrast, in the case of unsubstituted phthalocyanine only formation of double-decker complex was observed. The method was found to be limited for the preparation of complexes, containing porphyrins with unsubstituted meso-positions because of their degradation upon reaction course as well as porphyrins with bulky meso-substituents as a result of steric hindrances.

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Revisiting the One-Step Synthesis of Heteroleptic Lanthanide(III) (Porphyrinato)(Phthalocyaninates): Opportunities and Limitations

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