Synthesis of New Bioinorganic Systems Based on Nitrilium Derivatives of closo-Decaborate Anion and meso-Arylporphyrins with Pendant Amino Groups

Artem V. Ezhov,^a Fedor Yu. Vyal’ba,^a Ilya N. Kluykin,^b Kseniya A. Zhdanova,^a^@1 Natal’ya A. Bragina,^a Andrey P. Zhdanov,^b Konstantin Yu. Zhizhin,^b@2 Andrey F. Mironov,^a and Nikolay T. Kuznetsov^b

Dedicated to Academician Aslan Yu. Tsivadze on the ocassion of his 75th Birthday

^aMoscow Technological University (MITHT), 119571 Moscow, Russian Federation

^bN.S. Kournakov Institute of General and Inorganic Chemistry of Russian Academy of Sciences (IGIC RAS), 119991 Moscow, Russian Federation

^@1E-mail: zhdanova_k@mirea.ru

^@2E-mail: zhizhin@igic.ras.ru

DOI: 10.6060/mhc171254z

Macroheterocycles 2017 10(4-5) 505-509

In this work we elaborated an approach to the synthesis of meso-arylporphyrin with pendant amino groups. This approach is based on the preliminary functionalization of 4-(4-bromobutyloxy)benzaldehyde by potassium phthalimide, its condensation with pyrrole and removing the protecting phthalimide group. New boron-porphyrin conjugates were synthesized based on final aminoporphyrin and closo-decaborate anion [B₁₀H₁₀]^2-. New conjugates were obtained using microwave synthesis which reduced reaction time in 2 fold. Spectral properties of the conjugates were evaluated based on electron absorption spectra and steady-state fluorescence.

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Synthesis of New Bioinorganic Systems Based on Nitrilium Derivatives of closo-Decaborate Anion and meso-Arylporphyrins with Pendant Amino Groups

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