Thiadiazole Fused Subporphyrazines as Acceptors in Organic Photovoltaic Cells

Georgy L. Pakhomov,^a,b Vlad V. Travkin,^a Mahmoud Hamdoush,^b Yuriy A. Zhabanov,^band Pavel A. Stuzhin^b@

Dedicated to Academician Aslan Yusupovich Tsivadze on the occasion of his Birthday

^aInstitute for Physics of Microstructures of the Russian Academy of Sciences (IPM RAS), 603905 Nizhny Novgorod, Russian Federation

^bInstitute of Macroheterocycles, Ivanovo State University of Chemistry and Technology (ISUCT), 153000 Ivanovo, Russian Federation

^@Corresponding author E-mail: stuzhin@isuct.ru

DOI: 10.6060/mhc171038s

Macroheterocycles 2017 10(4-5) 548-551

A series of archetypal photovoltaic cells with a fully-subporphyrinoid planar heterojunction was fabricated by the thermal vacuum evaporation technique. The donor component of this junction was a boron subphthalocyanine chloride, while the acceptor component was perfluorinated subphthalocyanine or its heterocyclic analogues in which one, two or three tetrafluorobenzene ring(s) were substituted by the 1,2,5-thiadiazole ring(s) using the recently described synthetic approach. The photovoltaic parameters of such cells were measured and compared to those of the reference cell with the conventional fullerene C₆₀ as electron acceptor.

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Thiadiazole Fused Subporphyrazines as Acceptors in Organic Photovoltaic Cells

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