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Diazo Compounds in the Synthesis of O- and S-Containing Macroheterocycles

Gulnara Z. Raskildina,a Simon S. Zlotsky,a and Rimma M. Sultanovaa,b@
aUfa State Petroleum Technological University, 450062 Ufa, Russia
bUfa Institute of Chemistry of the Russian Academy of Sciences, 450054 Ufa, Russia
@Corresponding author E-mail: sultanova_rm@anrb.ru
 
DOI: 10.6060/mhc170622s
Macroheterocycles 2018 11(2) 166-172
 

The review summarizes, systematizes and analyzes literature data of the synthesis of oxygen- and sulfur-containing macroheterocyclic systems using Rh and Cu-catalyzed reactions of diazocarbonyl compounds over the last 15-20 years. The review considers the intra- and intermolecular reactions of introduction of diazocarbonyl compounds, which are used in synthesis of practically important biologically active compounds, via the C-O and C-S bonds.

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