Impact Factor 2021 = 1.200 has been issued by ISI Web of Knowledge (JCR 2021).

SCImago Journal & Country Rank

ISSN 1998-9539

Molecular Tectonics: Manganese(II), Copper(II) and Zinc(II) 1D Coordination Polymers Based on Tetramercaptothiacalix[4]arene Bearing Benzoate Coordinating Groups

A. S. Ovsyannikov,a,c@1 S. Ferlay,b@2 S. E. Solovieva,a,c I. S. Antipin,a,c A. I. Konovalov,a N. Kyritsakas,b and M. W. Hosseinib@3
aKazan Federal University, 420008 Kazan, Russian Federation
bMolecular Tectonics Laboratory, Université de Strasbourg, CNRS, CMC UMR 7140, F-67000 Strasbourg, France
cA.E. Arbuzov Institute of Organic and Physical Chemistry of Kazan Scientific Centre of Russian Academy of Sciences, 420088 Kazan, Russian Federation
@1Corresponding author E-mail:
@2Corresponding author E-mail:
@3Corresponding author E-mail:
DOI: 10.6060/mhc170295o
Macroheterocycles2017 10(2) 147-153
The combination under mild conditions of the carboxylic appended tetramercaptotetrathiacalix[4]arene (TMTCA) derivative 2 blocked in 1,3-A conformation with acetate salts of octahedral copper(II), manganese(II) and zinc(II), and pyridine, leads to the formation of new 1D coordination polymers in the crystalline state. Whereas for copper(II) and manganese(II) 1D linear coordination polymers are observed, for zinc(II) a zigzag chain has been evidenced. 


mhc170295o.pdf2.27 MB