Impact Factor 2021 = 1.200 has been issued by ISI Web of Knowledge (JCR 2021).

SCImago Journal & Country Rank

ISSN 1998-9539

Flexible Amide-Bonded Zn(II) Porphyrin Dimer: Electronic Structure Investigation and Its Induced Chirality

Mingfeng Qin,a Minzhi Li,a Weihua Zhu,a@1 Li Xu,a and Xu Lianga,b@2
aSchool of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, P. R. China
bState Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210000, P. R. China
@1Corresponding author E-mail:
@2Corresponding author E-mail:
DOI: 10.6060/mhc170292l
Macroheterocycles 2017 10(3) 301-307
In this paper, an in-depth electronic structure study of a xanthene-bridged and amide-bonded Zinc(II) porphyrin dimer (ZnII dimer) by solvent/anion dependent spectroscopy, electrochemistry and spectroelectrochemistry has been described. In addition, the self-assembly behaviors between this ZnII dimer and chiral (1S,2S)-(+)- and (1R,2R)-(–)-1,2-diaminocyclohexane exhibited distinctive derivative-shaped band morphology of the pseudo-Faraday-A1 terms on the MCD spectra, and the molecular polarization could be modulated by the chirality of guest chiral diamines.


mhc170292l.pdf1.77 MB