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ISSN 1998-9539

Template Synthesis and X-Ray Structure of the First Cobalt(II) Glyoximate Clathrochelate with Terminal Formyl Groups

Genrikh E. Zelinskii,a Alexander S. Belov,a Anna V. Vologzhanina,a Valentin V. Novikov,a Alexander A. Pavlov,a Yan V. Zubavichus,b and Yan Z. Voloshina,c@

aNesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, 119991 Moscow, Russia

bNational Research Center ‘‘Kurchatov Institute’’, 123182 Moscow, Russia

cI.M. Gubkin Russian State University of Oil and Gas, 119991 Moscow, Russia

@Corresponding author E-mail:


DOI: 10.6060/mhc161174v

Macroheterocycles 2016 9(4) 402-405


Cobalt(II) tris-glyoximate clathrochelate CoGm3(B4-C6H4CHO)2 with terminal reactive formyl group was obtained in moderate yield using direct template cross-linking of three molecules of glyoxime with 4-formylphenylboronic acid on a cobalt(II) ion as a matrix. Its molecular structure has been determined using single-crystal X-ray diffraction experiment.


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