Template Synthesis and X-Ray Structure of the First Cobalt(II) Glyoximate Clathrochelate with Terminal Formyl Groups

Genrikh E. Zelinskii,^a Alexander S. Belov,^a Anna V. Vologzhanina,^a Valentin V. Novikov,^a Alexander A. Pavlov,^a Yan V. Zubavichus,^b and Yan Z. Voloshin^a,c@

^aNesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, 119991 Moscow, Russia

^bNational Research Center ‘‘Kurchatov Institute’’, 123182 Moscow, Russia

^cI.M. Gubkin Russian State University of Oil and Gas, 119991 Moscow, Russia

^@Corresponding author E-mail: voloshin@ineos.ac.ru

DOI: 10.6060/mhc161174v

Macroheterocycles 2016 9(4) 402-405

Cobalt(II) tris-glyoximate clathrochelate CoGm₃(B4-C₆H₄CHO)₂ with terminal reactive formyl group was obtained in moderate yield using direct template cross-linking of three molecules of glyoxime with 4-formylphenylboronic acid on a cobalt(II) ion as a matrix. Its molecular structure has been determined using single-crystal X-ray diffraction experiment.

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Template Synthesis and X-Ray Structure of the First Cobalt(II) Glyoximate Clathrochelate with Terminal Formyl Groups

References: