Electrophilic Addition of Polyaromatic o-Quinones to an Iron(II) Diaminoclathrochelate Leading to the Macrobicyclic Iron(II) tris-Dioximates with Extended Annulated Ribbed Substituents

Aleksey B. Burdukov,^a@ Mikhail A. Vershinin,^a Natalie V. Pervukhina,^a Nataliya V. Kuratieva,^a Ilia V. Eltsov,^b Yan Z. Voloshin,^c and Pavel E. Plyusnin^a,b

^aNikolaev Institute of Inorganic Сhemistry SB RAS, 630090 Novosibirsk, Russia

^bNovosibirsk State University, 630090 Novosibirsk, Russia

^cNesmeyanov Institute of Organoelement Compounds RAS, 119991 Moscow, Russia

^@Corresponding author E-mail: lscc@niic.nsc.ru

DOI: 10.6060/mhc161068b

Macroheterocycles2016 9(4) 406-412

Macrobicyclic iron(II) tris-dioximate with two inherent amino groups undergoes electrophilic addition with 1,10-phenanthroline-5,6-dione and phenanthrene-9,10-dione to give a cage complexes with extended ribbed substituents. These clathrochelates have been characterized using single crystal XRD, multinuclear NMR and other spectral techniques. They have been found to undergo the ligand-centered redox processes; the obtained phenanthroline-containing iron(II) cage complex is proposed as a potent chelating clathrochelate ligand.

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Electrophilic Addition of Polyaromatic o-Quinones to an Iron(II) Diaminoclathrochelate Leading to the Macrobicyclic Iron(II) tris-Dioximates with Extended Annulated Ribbed Substituents

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