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ISSN 1998-9539

Electrophilic Addition of Polyaromatic o-Quinones to an Iron(II) Diaminoclathrochelate Leading to the Macrobicyclic Iron(II) tris-Dioximates with Extended Annulated Ribbed Substituents

Aleksey B. Burdukov,a@ Mikhail A. Vershinin,a Natalie V. Pervukhina,a Nataliya V. Kuratieva,a Ilia V. Eltsov,b Yan Z. Voloshin,c and Pavel E. Plyusnina,b

aNikolaev Institute of Inorganic Сhemistry SB RAS, 630090 Novosibirsk, Russia

bNovosibirsk State University, 630090 Novosibirsk, Russia

cNesmeyanov Institute of Organoelement Compounds RAS, 119991 Moscow, Russia

@Corresponding author E-mail: 


DOI: 10.6060/mhc161068b

Macroheterocycles2016 9(4) 406-412


Macrobicyclic iron(II) tris-dioximate with two inherent amino groups undergoes electrophilic addition with 1,10-phenanthroline-5,6-dione and phenanthrene-9,10-dione to give a cage complexes with extended ribbed substituents. These clathrochelates have been characterized using single crystal XRD, multinuclear NMR and other spectral techniques. They have been found to undergo the ligand-centered redox processes; the obtained phenanthroline-containing iron(II) cage complex is proposed as a potent chelating clathrochelate ligand.


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