The Direct Synthesis of 2-N-Methyl-5,10,15,20-tetrakis-(4′-sulfophenyl)-2-aza-21-carbaporphyrin J-Aggregates

Vladimir B. Sheinin,^a@ Olga M. Kulikova,^a Viktor V. Aleksandriiskii,^b and Oscar I. Koifman^a,b

^aG.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, 153045 Ivanovo, Russia

^bIvanovo State University of Chemistry and Technology, 153000 Ivanovo, Russia

^@Corresponding author E-mail: vbs@isc-ras.ru

DOI: 10.6060/mhc161067s

Macroheterocycles2016 9(4) 353-360

Here we present the way of synthesis of very stable J-aggregates based on water-soluble 2-N-methyl-5,10,15,20-tetrakis-(4′-sulfophenyl)-2-aza-21-carbaporphyrin zwitter-ion, which are formed as the main product of 2-N-methyl-5,10,15,20-tetraphenyl-2-aza-21-carbaporphyrin sulfonation by sulfuric acid. J-Aggregates and corresponding monomer were obtained for the first time and characterized using UV-Vis, ¹H NMR, MALDI-TOF, ESI-MS analysis.

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The Direct Synthesis of 2-N-Methyl-5,10,15,20-tetrakis-(4′-sulfophenyl)-2-aza-21-carbaporphyrin J-Aggregates

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