Synthesis and Spectral Properties of New Octamethyl Substituted Tetrapyrazinoporphyrazines

Anton D. Kosov,^a Tatiana V. Dubinina,^a,b@Mikhail Yu. Seliverstov,^a Larisa G. Tomilova,^a,b and Nikolay S. Zefirov^a,b

^aDepartment of Chemistry, M.V. Lomonosov Moscow State University, 119991 Moscow, Russian Federation.

^bInstitiute of Physiologically Active Compounds, Russian Academy of Science, 142432 Chernogolovka, Moscow Region, Russian Federation

^@Corresponding author E-mail: dubinina.t.vid@gmail.com

DOI: 10.6060/mhc160535d

Macroheterocycles 2016 9(2) 201-205

Efficient synthetic approach to a new magnesium and zinc complexes of methyl substituted tetrapyrazinoporphyrazine was developed. The optimization of reaction conditions for preparation of initial pyrazine-2,3-dicarbonitrile was carried out, using cerium ammonium nitrate as a catalyst. The target complexes were characterized by MALDI-TOF mass spectrometry and NMR spectroscopy. Spectral properties were investigated using UV-Vis and fluorescence spectroscopy.

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Synthesis and Spectral Properties of New Octamethyl Substituted Tetrapyrazinoporphyrazines

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