The Upper Rim Functionalized Calixarene Ketocyanines: Synthesis, Structure and Fluorescence Properties

Yuriy Matvieiev,^a Andrii Kulinich,^a Aleksey Ryabitskii,^a Svitlana Shishkina,^b Oleg Shishkin,^b Vasyl Pivovarenko,^c and Vitaly Kalchenko^a@

^aInstitute of Organic Chemistry, National Academy of Sciences of Ukraine, 02660 Kyiv, Ukraine

^bInstitute for Single Crystals, National Academy of Sciences of Ukraine, 61001 Kharkiv, Ukraine

^cChemical Faculty, Taras Shevchenko National University of Kyiv, 01601 Kyiv, Ukraine

^@Corresponding author E-mail: vik@ioch.kiev.ua

DOI: 10.6060/mhc160533k

Macroheterocycles 2016 9(3) 288-293

The calix[4]arene ketocyanine receptors bearing nitro-, amino- or urea moiety at the wide macrocycle rim were elaborated. Their molecular structures, UV-Vis absorption and fluorescence properties were studied. The estimated solvatofluorochromism levels and quantum yield values demonstrate clearly a possibility of control of the fluorescence colour and intensity by varying the nature of the analyte bound in the proximity of the fluorophore ketocyanine unit.

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The Upper Rim Functionalized Calixarene Ketocyanines: Synthesis, Structure and Fluorescence Properties

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