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ISSN 1998-9539

Transition Metal Catalysis in Porphyrin Modifications

Alexei D. Averin,a,b Alexei A. Yakushev,b and Irina P. Beletskayaa,b@
aM.V. Lomonosov Moscow State University, Department of Chemistry, 119991 Moscow, Russia
bA.N. Frumkin Institute of Physical Chemistry and Electrochemistry, 119991 Moscow, Russia
@Corresponding author E-mail:
DOI: 10.6060/mhc160532a
Macroheterocycles 2016 9(2) 108-120
A mini-review covers the results obtained by the authors in porphyrin modifications using Pd and Cu-catalyzed amination of halogenophenyl substituted porphyrins. Amination using primary and secondary linear and cyclic amines and diamines, formation of polymacrocyclic conjugates of aza- and diazacrown ethers and diazacrown ether-based cryptands with porphyrins are addressed. Synthesis of diporphyrin and triporphyrin systems via Pd-catalyzed amination and Cu-catalyzed “click” reactions are discussed.



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