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ISSN 1998-9539

Phenyl Substituted Porphyrins. 6. Acylation of Alcohols with Carboxyphenylporphyrins

Mariya A. Salnikova,a Tatiana V. Lubimova,b Sergei A. Syrbu,a and Alexander S. Semeikina@
aResearch Institute of Macroheterocycles, Ivanovo State University of Chemistry and Technology, 153000 Ivanovo, Russia
bInstitute of Solution Chemistry, Russian Academy of Sciences, 153045 Ivanovo, Russia
@Corresponding author E-mail:
DOI: 10.6060/mhc151086s
Macroheterocycles 2016 9(2) 141-150
Pyrrolic precursors and benzaldehydes were used to afford meso-carboxyphenylporphyrins bearing one or four carboxyl groups. The reaction conditions for the acylation of alcohols with the obtained carboxyphenylporphyrins in the presence of carbodiimides were studied. Optimal reaction conditions were found and a series of phenylporphyrin esters of various structure was synthesized.



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