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ISSN 1998-9539

Synthesis of Macroheterocyclic Compounds with a Furan Bridge Possessing Structural Fragments of 1,2,3-Triazoles and Natural Diterpenoids

Yuri V. Kharitonov,a,b Makhmut M. Shakirov,a and Elvira E. Shultsa,b@

aNovosibirsk Institute of Organic Chemistry, 630090 Novosibirsk, Russia

bNovosibirsk State University, 630090 Novosibirsk, Russia

@Corresponding author E-mail: schultz@nioch.nsc.ru

 

DOI: 10.6060/mhc141138s
Macroheterocycles 2015 8(1) 81-88

 

Derivatives of natural diterpenoid lambertianic acid containing alkyne and dialkyne substituent in the furan ring were obtained. 1,2,3-Triazole-incarporated furan bridged macrocycles have been prepared by 1,3-dipolar cycloaddition of methyl 15,16-bis[(prop-2-yn-1-yloxy)methyl]lambertianate with various diazides in the presence of Cu(II)/sodium ascorbate in methylene chloride/water reaction medium.

 

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