Porphyrin Core Dendrimers with Ether-Linked Carbazole Dendrons: Dual Luminescence of Core and Conformational Flexibility of Dendritic Shell

Nguyen Tran Nguyen,^a Eduardo Coutiño-Gonzalez,^b Johan Hofkens,^b Ivan G. Scheblykin,^c Wim Dehaen,^a and Mikalai Kruk^d@

Dedicated to the Corresponding member of Russian Academy of Sciences Prof. Oscar Koifman on the occasion of his 70th Anniversary

^aMolecular Design and Synthesis, Department of Chemistry, KU Leuven, Celestijnenlaan 200F, B-3001 Leuven, Belgium

^bMolecular Imaging and Photonics, Department of Chemistry, KU Leuven, Celestijnenlaan 200F, B-3001 Leuven, Belgium

^cLund University, Department of Chemical Physics, P.O. Box 124, 22100 Lund, Sweden

^dBelarusian State Technological University, Physics Department, 220006 Minsk, Belarus

^@Corresponding author E-mail: krukmikalai@yahoo.com

DOI: 10.6060/mhc140717k
Macroheterocycles 2014 7(3) 240-248

The ground state absorption spectra, spectra and lifetimes of the luminescence originating from the lowest S1 (Q(0,0)) and higher S2 (B) excited states of porphyrin core in the dendrimers with ether-linked carbazole dendrons have been studied in detail. The relationship between the molecular design of the dendritic shell and the optical features of the dendrimer core in solution is presented. The influence of the axial ligation of the porphyrin core and the conformational flexibility of the dendritic shell on the luminescent properties of the studied dendrimers is revealed.

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Porphyrin Core Dendrimers with Ether-Linked Carbazole Dendrons: Dual Luminescence of Core and Conformational Flexibility of Dendritic Shell

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