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ISSN 1998-9539

Reactivity of Rare Earth Metal Porphyrins/Phthalocyanines in Acid Media

Tatyana N. Lomova,a@ Marija E. Klyueva,b and Oskar I. Koifmana,c

aG. A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, 153045 Ivanovo, Russia

bIvanovo State Medical Academy, 153000 Ivanovo, Russia

cIvanovo State University of Chemistry and Technology, Research Institute of Macroheterocycles, 153000 Ivanovo, Russia

@Corresponding author E-mail:


DOI: 10.6060/mhc140599l
Macroheterocycles 2015 8(1) 32-46


Synthesis, structure, spectral properties and behavior in acid media of acido phthalocyanine complexes (X)n-2MPc, double- and triple-decker phthalocyanine and porphyrin complexes M(HPc)(Pc), M(Pc)2, M2(Pc)3, and M(P)2, M2(P)3 (M - lanthanide or actinide cation) were explored using UV-visible, IR, NMR spectroscopy and chemical kinetics. Kinetic equations, stoichiometric mechanisms of complexes demetallation and stability- structure relations were established.



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