Reactivity of Rare Earth Metal Porphyrins/Phthalocyanines in Acid Media

Tatyana N. Lomova,^a@ Marija E. Klyueva,^b and Oskar I. Koifman^a,c

^aG. A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, 153045 Ivanovo, Russia

^bIvanovo State Medical Academy, 153000 Ivanovo, Russia

^cIvanovo State University of Chemistry and Technology, Research Institute of Macroheterocycles, 153000 Ivanovo, Russia

^@Corresponding author E-mail: tnl@isc-ras.ru

DOI: 10.6060/mhc140599l
Macroheterocycles 2015 8(1) 32-46

Synthesis, structure, spectral properties and behavior in acid media of acido phthalocyanine complexes (X)_n-2MPc, double- and triple-decker phthalocyanine and porphyrin complexes M(HPc)(Pc), M(Pc)₂^•, M₂(Pc)₃, and M(P)₂, M₂(P)₃ (M - lanthanide or actinide cation) were explored using UV-visible, IR, NMR spectroscopy and chemical kinetics. Kinetic equations, stoichiometric mechanisms of complexes demetallation and stability- structure relations were established.

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