Реакционная способность комплексов редкоземельных металлов с порфиринами и фталоцианинами в кислых средах

Т. Н. Ломова,^a@ М. Е. Клюева,^b О. И. Койфман^a,c

^aИнститут химии растворов им. Г.А. Крестова РАН, 153045 Иваново, Россия

^bИвановская государственная медицинская академия, 153000 Иваново Россия

^сИвановский государственный химико-технологический университет, НИИ макрогетероциклических соединений, 153000 Иваново, Россия

^@E-mail: tnl@isc-ras.ru

DOI: 10.6060/mhc140599l
Макрогетероциклы 2015 8(1) 32-46

Синтез, спектроскопия, молекулярная структура и поведение в кислотах (ацидо)(фталоцианинато), (фталоцианинато)/(порфиринато)комплексов лантанидов(III), тория и урана(III)/(IV) двух- и трехпалубного строения изучены с использованием УФ-видимой, ИК, ЯМР-спектроскопии и химической кинетики. Расширено понимание взаимосвязи между структурой и стабильностью комплексов.

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Реакционная способность комплексов редкоземельных металлов с порфиринами и фталоцианинами в кислых средах

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