On a Way to New Types of the Hybrid Polyazomethine-Pyrazolate Metal Pseudomacrobicyclic Complexes: the Synthesis and Structure of Their Ligand Synthones

Svitlana V. Kats,^a Oleg A. Varzatskii,^b Larysa V. Penkova,^a Anna V. Vologzhanin^a,^c Valentin V. Novikov,^c Ekaterina G. Lebed,^c and Yan Z. Voloshin^c@

^aTaras Shevchenko National University of Kyiv, 01601 Kyiv, Ukraine

^bVernadskii Institute of General and Inorganic Chemistry of the National Academy of Sciences of Ukraine, 03680 Kyiv, Ukraine

^cNesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, 119991 Moscow, Russia

^@Corresponding author E-mail: voloshin@ineos.ac.ru

DOI: 10.6060/mhc140485v

Macroheterocycles 2014 7(1) 34-39

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3-Acetylpyrazole hydrazone, its formyl- and carboxymethyl-containing analogs and the bis-pyrazolyl azine derivative were obtained by condensation. They were described to be suitable organic synthones for the synthesis of mono- and binuclear hybrid polyazomethine-pyrazolate metal complexes.

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On a Way to New Types of the Hybrid Polyazomethine-Pyrazolate Metal Pseudomacrobicyclic Complexes: the Synthesis and Structure of Their Ligand Synthones

References