Synthesis of Trismacrocyclic and Macrotricyclic Compounds Possessing Structural Fragments of Aza- and Diazacrown Ethers, Cyclen and Cyclam via Pd-Catalyzed Amination Reactions

Sergei M. Kobelev,^a Alexei D. Averin,^a,b@ Alexei K. Buryak,^b Franck Denat,^c Roger Guilard,^c and Irina P. Beletskaya^a,b

^aM.V. Lomonosov Moscow State University, Department of Chemistry, 119991 Moscow, Russia

^bA.N. Frumkin Institute of Physical and Electrochemistry of RAS, 119991 Moscow, Russia

^cInstitut de Chimie Moléculaire de l’Université de Bourgogne (ICMUB), UMR CNRS 6302, 21078 Dijon Cedex, France

^@Corresponding author E-mail: averin@org.chem.msu.ru

DOI: 10.6060/mhc140484a

Macroheterocycles 2014 7(1) 28-33

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Using the Pd-catalyzed amination of substituted cyclen and cyclam derivatives with azacrown ethers trismacrocyclic compounds having a central tetraazamacrocyclic core were obtained, while reaction with diazacrown ethers affords cylindrically-shaped cryptands.

References

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Synthesis of Trismacrocyclic and Macrotricyclic Compounds Possessing Structural Fragments of Aza- and Diazacrown Ethers, Cyclen and Cyclam via Pd-Catalyzed Amination Reactions

References