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ISSN 1998-9539

Synthesis of Trismacrocyclic and Macrotricyclic Compounds Possessing Structural Fragments of Aza- and Diazacrown Ethers, Cyclen and Cyclam via Pd-Catalyzed Amination Reactions

Sergei M. Kobelev,a Alexei D. Averin,a,b@ Alexei K. Buryak,b Franck Denat,c Roger Guilard,c and Irina P. Beletskayaa,b
aM.V. Lomonosov Moscow State University, Department of Chemistry, 119991 Moscow, Russia 
bA.N. Frumkin Institute of Physical and Electrochemistry of RAS, 119991 Moscow, Russia 
cInstitut de Chimie Moléculaire de l’Université de Bourgogne (ICMUB), UMR CNRS 6302, 21078 Dijon Cedex, France
@Corresponding author E-mail: 
DOI: 10.6060/mhc140484a
Macroheterocycles 2014 7(1) 28-33


Using the Pd-catalyzed amination of substituted cyclen and cyclam derivatives with azacrown ethers trismacrocyclic compounds having a central tetraazamacrocyclic core were obtained, while reaction with diazacrown ethers affords cylindrically-shaped cryptands.



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