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ISSN 1998-9539

Synthesis of Macropolycycles Comprising Diazacrown and Adamantane Moieties via Pd -Catalyzed Amination Reaction

Alexei A. Yakushev,a,b Maksim V. Anokhin,a Alexei D. Averin,a,b@ Olga A. Maloshitskaya,a Evgenii N. Savelyev,c Gennadii M. Butov,d Boris S. Orlinson,c Ivan A. Novakov,c and Irina P. Beletskayaa,b


aLomonosov Moscow State University, Department of Chemistry, 119991 Moscow, Russia
bA.N. Frumkin Institute of Physical and Electrochemistry, 119991 Moscow, Russia
cVolgograd State Technical University, 400131 Volgograd, Russia
dVolzhsky Polytechnical Institute (Branch) of Volgograd State Technical University, 404131 Volzhsky, Russia


@Corresponding authorE-mail:


Macroheterocycles 2013 6(1) 40-46


DOI: 10.6060/mhc121214a




N,N’-Bis(bromobenzyl) substituted diazacrown ethers were obtained in the reactions of corresponding free diaza-crowns with two equivalents of bromobenzyl bromides in high yields. These compounds were introduced in the Pd-catalyzed amination reaction with 1,3-bis(aminomethyl) and 1,3-bis(2-aminoethyl)adamantanes to give macrobicyclic products.



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