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ISSN 1998-9539

Halogenation of Benzocrown Ethers by Hypohalites in Aqueous Solutions

Sergei M. Pluzhnik-Gladyr


A.V. Bogatsky Physico-Chemical Institute of National Academy of Sciences of Ukraine, 65080 Odessa, Ukraine




Macroheterocycles 2012 5(4-5) 384-388 


DOI: 10.6060/mhc2012.121103p


NaClO and NaBrO can be used as soft and selective reagents for chlorination and bromination of benzocrown ethers (BCE) in a water medium. The adjustment of pH in these processes enables the control of the resulting number of atoms of halogens in the aromatic fragment of BCE.


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