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ISSN 1998-9539

Cobalt Phthalocyanine – аn Effective Catalyst of Hydrogen Production from Formic Acid

Evgeny V. Kudrik,@1 Sergei V. Makarov,@2 Elena S. Ageeva, and Ilia A. Dereven’kov


Ivanovo State University of Chemistry and Technology, Ivanovo, 153000, Russia


@1Corresponding author E-mail: ttos@isuct.ru

@2Corresponding author E-mail: makarov@isuct.ru


Cobalt tetrasulfophthalocyanine, CoII(TSPc)4-, is shown to be an effective catalyst of decomposition of formic acid to
hydrogen and carbon dioxide. The overall mechanism comprises the reduction of CoII(TSPc)4-, followed by the reaction
of intermediate complex CoI(TSPc)5- with proton.

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