Porphyrazines with Annulated Diazepine Rings. 3. MgII Complex of 4-tert-Butylphenyl Substituted Tetra(1,4-diazepino)porphyrazine: Synthesis and Peculiar Effect of Solvent on Its Spectral Properties

P. A. Tarakanov,^a M. P. Donzello,^b O. I. Koifman,^a P. A. Stuzhin^a@

^aDeparment of Organic Chemistry, Ivanovo State University of Chemical Technology, 153000 Ivanovo, Russia

^bDipartimento di Chimica, Universita di Roma “La Sapienza”, P-le Aldo Moro, 5, I-00185 Rome, Italy

^@Corresponding author E-mail: stuzhin@isuct.ru

Macroheterocycles 2011 4(3) 177-183

Received 30.07.2011
Accepted 26.08.2011

Mg^II complex of 4-tert-butylphenyl substituted tetra(1,4-diazepino)porphyrazine exists as monomer only in diluted solutions in aprotic solvents (DMF, DMSO), while in other organic solvents (CH₂Cl₂, THF, pyridine) the stable dimer is formed, presumably due to intermolecular H-bonding with water.

http://dx.doi.org/10.6060/mhc2011.3.06

MHC2011_t04n03_177-183.pdf (1.73 MB)

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