Intercalation of 5,10,15,20-Tetrakis[1-(3-sulfonatopropyl)-4-pyridiniumyl]porphyrins into V2O5·nH2O

Olga N. Suvorova,^a Dieter Wöhrle,^b Elena A. Shupak,^a Alexander I. Kirillov,^a Tat´yana I. Lopatina,^a and Galina S. Zabrodina^a@

^aRussian Academy of Sciences, Institute of Organometallic Chemistry, 603950 Nizhnii Novgorod, Russia

^bUniversität Bremen, Institut für Organische und Makromolekulare Chemie, 28334 Bremen, Germany

^@Corresponding author E-mail: kudgs@mail.ru

DOI: 10.6060/mhc2010.2-3.134

New intercalation compounds based on zwitterionic tetrakis[1-(3-sulfonatopropyl)-4-pyridiniumyl]porphyrins and xerogel V₂O₅·nH₂O have been obtained. These compounds were characterized by methods of X-ray diffraction, thermogravimetric analysis, IR-spectroscopy and scanning electron microscopy.

Keywords: Intercalation, vanadium pentoxide xerogel, porphyrin, structure, orientation.

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