Low Temperature Spectroscopic Study of the Sulfides Binding by Dioxygen Adduct of Cobalt Porphyrin

Garik G. Martirosyan,^a@ Astghik A. Hovhannisyan,^a Arsen S. Azizyan,^a Gohar S. Hovhannisyan,^a and Alexei V. Iretskii^b

^aThe Scientific Technological Centre of Organic and Pharmaceutical Chemistry NAS RA, Molecule Structure Research Centre, 0014 Yerevan, Armenia

^bLake Superior State University, Department of Chemistry, Sault Ste. Marie, MI 49783, USA

^@Corresponding author E-mail: ggmartirosyan@gmail.com

DOI: 10.6060/mhc214035m
Macroheterocycles 2021 14(4) 280-285

Dedicated to the blessed memory of our beloved leader, colleague and friend Tigran Kutikyan

The interaction of dimethyl sulfide ((CH₃)₂S) and hydrogen sulfide (H₂S) with cobalt porphyrin and its five-coordinate dioxygen complex was studied at low temperatures in sublimated porphyrin layers using electronic and infrared absorption spectroscopy. Upon addition of sulfides to a cryostat containing Co(TTP)O₂ (TTP is meso-tetratolyl-porphyrinato dianion) at low temperatures, the FTIR and Vis electronic spectral changes were observed which are consistent with sulfide binding in axial trans-position to dioxygen. Density functional theory (DFT) computational analysis also supports formation of the six-coordinate adducts. These complexes are stable only at low temperatures and dissociate upon heating.

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Low Temperature Spectroscopic Study of the Sulfides Binding by Dioxygen Adduct of Cobalt Porphyrin

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