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ISSN 1998-9539

Preparation and Synchrotron X-Ray Structure of an Apically- and Ribbed-Functionalized Iron(II) Clathrochelate Decorated with Six Methoxyl and Two Carboxyl Terminal Groups

Ilya P. Limarev,a,b Genrikh E. Zelinskii,a,b@ Anna V. Vologzhanina,b Yan V. Zubavichus,c and Yan Z. Voloshina,b
 
aKurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, 119991 Moscow, Russia
bNesmeyanov Institute of the Organoelement Compounds RAS, 119991 Moscow, Russia
cBoreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russia
@Corresponding author E-mail: heinrichzelinskiy@gmail.com
 

Octafunctionalized iron(II) cage complex with six equivalent methoxyl-terminated alkylsulfide ribbed fragments and two terminal carboxyl groups in its apical aromatic substituents was obtained using nucleophilic substitution of an appropriate hexachloroclathrochelate precursor with an anionic derivative of mercaptoacetic acid; generated in situ in the presence of triethylamine, followed by the further esterification reaction of thus obtained product with methanol. The obtained diamagnetic cage complex was characterized using elemental analysis, MALDI-TOF mass spectrometry, UV-Vis and 1H NMR spectra, and by the synchrotron single crystal X-ray diffraction experiment as well.

 

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