Unusual Cyan-Purple Electrochromism of Sandwich Phthalocyaninates Observed on the Example of µ-Carbido Diruthenium(IV) Complex

Daria S. Kutsybala,^a Alexander V. Shokurov,^a@ Andrey P. Kroitor,^a Alexander G. Martynov,^a Sofia L. Selektor,^a Aslan Yu.Tsivadze,^a,b and Yulia G. Gorbunova^a,b

^aA.N. Frumkin Institute of Physical Chemistry and Electrochemistry of Russian Academy of Sciences, 119071 Moscow Russia

^bN.S. Kurnakov Institute of General and Inorganic Chemistry of Russian Academy of Sciences, 119071 Moscow, Russia

^@Corresponding author E-mail: shokurov@phyche.ac.ru

DOI: 10.6060/mhc210234s

Macroheterocycles 2021 14(1) 51-58

Dedicated to the memory of Prof. Larisa G. Tomilova

Current research in sandwich phthalocyaninates enjoys increasing interest due to peculiar properties of these compounds, i.e. their intense coloration and ability to change and control it via redox processes. Obviously, such effect found its application in development of electrochromic devices. In the case of commonly studied rare earth element bisphthalocyaninates, the most dominant electrochromic palette observed for them lies within the red-green-blue gamut. In this work, we report that an unusual sandwich – covalently-bridged µ-carbido diruthenium(IV) bisphthalocyaninate – exhibits equally unusual color changes upon its reversible electrochemical oxidation/reduction, namely switching from cyan to purple. The study provides a detailed spectroelectrochemical characterization of this µ-carbido-dimeric complex in solution, in thin cast and ultrathin Langmuir-Schaefer films, which all demonstrate aforementioned variable vibrant coloration in action.

References:

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1. Kirin I.S., Moskalev P.N., Makashev Y.A. Russ. J. Inorg. Chem. 1965, 10, 1065-1066.

2. Weiss R., Fischer J. In: The Porphyrin Handbook, Vol 16, Elsevier, 2003. pp. 171-246.
https://doi.org/10.1016/B978-0-08-092390-1.50010-2

3. Pushkarev V.E., Tomilova L.G., Nemykin V.N. Coord. Chem. Rev. 2016, 319, 110-179.
https://doi.org/10.1016/j.ccr.2016.04.005

4. Koifman O.I., Ageeva T.A., Beletskaya I.P., Averin A.D., Yakushev A.A., Tomilova L.G., Dubinina T.V., Tsivadze A.Y., Gorbunova Y.G., Martynov A.G., Konarev D.V., Khasanov S.S., Lyubovskaya R.N., Lomova T.N., Korolev V.V., Zenkevich E.I., Blaudeck T., von Borczyskowski C., Zahn D.R.T., Mironov A.F., Bragina N.A., Ezhov A.V., Zhdanova K.A., Stuzhin P.A., Pakhomov G.L., Rusakova N.V., Semenishyn N.N., Smola S.S., Parfenyuk V.I., Vashurin A.S., Makarov S.V., Dereven'kov I.A., Mamardashvili N.Z., Kurtikyan T.S., Martirosyan G.G., Burmistrov V.А., Aleksandriiskii V.V., Novikov I.V., Pritmov D.A., Grin M.A., Suvorov N.V., Tsigankov A.A., Fedorov A.Y., Kuzmina N.S., Nyuchev A.V., Otvagin V.F., Kustov A.V., Belykh D.V., Berezin D.B., Solovieva A.B., Timashev P.S., Milaeva E.R., Gracheva Y.A., Dodokhova M.A., Safronenko A.V., Shpakovsky D.B., Syrbu S.A., Gubarev Y.A., Kiselev A.N., Koifman M.O., Lebedeva N.S., Yurina E.S. Macroheterocycles 2020, 13, 311-467.
https://doi.org/10.6060/mhc200814k

5. Chen X., Qi D., Liu C., Wang H., Xie Z., Chen T.W., Chen S.M., Tseng T.W., Jiang J. RSC Adv. 2019, 10, 317-322.
https://doi.org/10.1039/C9RA07847A

6. Martynov A.G., Polovkova M.A., Berezhnoy G.S., Sinelshchikova A.A., Dolgushin F.M., Birin K.P., Kirakosyan G.A., Gorbunova Y.G., Tsivadze A.Y. Inorg. Chem. 2020, 59, 9424-9433.
https://doi.org/10.1021/acs.inorgchem.0c01346

7. Birin K.P., Poddubnaya A.I., Gorbunova Y.G., Tsivadze A.Y. Macroheterocycles 2017, 10, 514-515.
https://doi.org/10.6060/mhc171258b

8. Bouvet M., Gaudillat P., Suisse J.-M. J. Porphyrins Phthalocyanines 2013, 17, 628-635.
https://doi.org/10.1142/S1088424613300048

9. Selektor S.L., Shokurov A.V., Arslanov V.V., Gorbunova Y.G., Raitman O.A., Isakova A.A., Birin K.P., Tsivadze A.Y. Russ. J. Electrochem. 2012, 48, 218-233.
https://doi.org/10.1134/S1023193512020164

10. Lindsey J.S., Bocian D.F. Acc. Chem. Res. 2011, 44, 638-650.
https://doi.org/10.1021/ar200107x

11. Martynov A.G., Safonova E.A., Tsivadze A.Y., Gorbunova Y.G. Coord. Chem. Rev. 2019, 387, 325-347.
https://doi.org/10.1016/j.ccr.2019.02.004

12. Selektor S.L., Shokurov A.V., Raitman O.A., Sheinina L.S., Arslanov V.V., Birin K.P., Gorbunova Y.G., Tsivadze A.Y. Colloid J. 2012, 74, 334-345.
https://doi.org/10.1134/S1061933X12020111

13. Shokurov A.V., Kutsybala D.S., Martynov A.G., Yagodin A.V., Gorbunova Y.G., Novikov D., Bakirov A.V., Shcherbina M.A., Chvalun S.N., Arslanov V.V. Selektor S. L. Macroheterocycles 2019, 12, 264-267.
https://doi.org/10.6060/mhc191071s

14. Wang H., Wang B.W., Bian Y., Gao S., Jiang J. Coord. Chem. Rev. 2016, 306, 195-216.
https://doi.org/10.1016/j.ccr.2015.07.004

15. Semenishyn N.N., Smola S.S., Rusakova N.V., Martynov A.G., Birin K.P., Gorbunova Y.G. Macroheterocycles 2018, 11, 262-268.
https://doi.org/10.6060/mhc180691r

16. Smola S.S., Rusakova N.V., Kamalov G.L., Gorbunova Y.G., Tsivadze A.Y. Macroheterocycles 2017, 10, 268-272.
https://doi.org/10.6060/mhc170621r

17. Corker G.A., Grant B., Clecak N. J. J. Electrochem. Soc. 1979, 126, 1339-1343.
https://doi.org/10.1149/1.2129273

18. Zhang J., Lu F., Huang H., Wang J., Yu H., Jiang J., Yan D., Wang Z. Synth. Met. 2005, 148, 123-126.
https://doi.org/10.1016/j.synthmet.2004.09.027

19. Rodríguez-Méndez M.L., Aroca R., DeSaja J.A. Chem. Mater. 1992, 4, 1017-1020.
https://doi.org/10.1021/cm00023a018

20. Selektor S.L., Shokurov A.V., Revina A.A., Arslanov V.V., Gorbunova Y.G., Tsivadze A.Y. Macroheterocycles 2015, 8, 135-142.
https://doi.org/10.6060/mhc150765s

21. Rodríguez-Méndez M.L., de Saja J.A. J. Porphyrins Phthalocyanines 2009, 13, 606-615.
https://doi.org/10.1142/S1088424609000814

22. Tang X., Liu Q., Wei C., Lv X., Jin Z., Chen Y., Jiang J. J. Rare Earths 2021, 39, 113-120.
https://doi.org/10.1016/j.jre.2020.11.004

23. Selektor S.L., Shokurov A.V. Prot. Met. 2015, 51, 171-203.
https://doi.org/10.1134/S2070205115020161

24. Selektor S.L., Sheinina L.S., Shokurov A.V., Raitman O.A., Arslanov V.V., Lapkina L.A., Gorbunova Y.G., Tsivadze A.Y. Prot. Met. 2011, 47, 447-456.
https://doi.org/10.1134/S2070205111040162

25. Tolbin A.Y., Pushkarev V.E., Tomilova L.G., Zefirov N.S. J. Porphyrins Phthalocyanines 2008, 12, 1187-1193.
https://doi.org/10.1142/S108842460800056X

26. Pushkarev V.E., Tolbin A.Y., Zhurkin F.E., Borisova N.E., Trashin S.A., Tomilova L.G., Zefirov N.S. Chem. Eur. J. 2012, 18, 9046-9055.
https://doi.org/10.1002/chem.201200361

27. Krichevsky D.M., Zasedatelev A.V., Tolbin A.Y., Luchkin S.Y., Karpo A.B., Krasovskii V.I., Tomilova L.G. Thin Solid Films 2017, 642, 295-302.
https://doi.org/10.1016/j.tsf.2017.10.001

28. Dubinina T.V., Belousov M.S., Maklakov S.S., Chernichkin V.I., Sedova M.V., Tafeenko V.A., Borisova N.E., Tomilova L.G. Dyes Pigm. 2019, 170, 107655.
https://doi.org/10.1016/j.dyepig.2019.107655

29. Korostei Y.S., Pushkarev V.E., Tolbin A.Y., Dzuban A.V., Chernyak A.V., Konev D.V., Medvedeva T.O., Talantsev A.D., Sanina N.A., Tomilova L.G. Dyes Pigm. 2019, 170, 107648.
https://doi.org/10.1016/j.dyepig.2019.107648

30. Tomilova L.G., Pushkarev V.E., Dubinina T.V., Tolbin A.Yu., Advances in the Synthesis and Study of the Properties of Phthalocyanines and Their Analogues, Moscow State University Publishing House, 2019.

31. Tomilova L.G., Gorbunova Y.G., Rodriguez-Mendez M.L., de Saja J.A. Mendeleev Commun. 1994, 4, 127-128.
https://doi.org/10.1070/MC1994v004n04ABEH000379

32. Gorbunova Y.G., Rodríguez-Méndez M.L., Souto J., Tomilova L.G., de Saja J.A. Chem. Mater. 1995, 7, 1443-1447.
https://doi.org/10.1021/cm00056a007

33. Gorbunova Y.G., Rodríguez-Méndez M.L., Kalashnikova I.P., Tomilova L.G., de Saja J.A., Rodríguez-Morgade M.S. Langmuir 2001, 17, 5004-5010.
https://doi.org/10.1021/la0102760

34. Ishikawa N. J. Porphyrins Phthalocyanines 2001, 05, 87-101.
https://doi.org/10.1002/1099-1409(200101)5:1<87::AID-JPP304>3.0.CO;2-Q

35. May A., Majumdar P., Martynov A.G., Lapkina L.A., Troyanov S.I., Gorbunova Y.G., Tsivadze A.Y., Mack J., Nyokong T. J. Porphyrins Phthalocyanines 2020, 24, 589-601.
https://doi.org/10.1142/S108842462050011X

36. Rousseau R., Aroca R., Rodríguez-Méndez M.L. J. Mol. Struct. 1995, 356, 49-62.
https://doi.org/10.1016/0022-2860(95)08905-B

37. Zhu P., Pan N., Ma C., Sun X., Arnold D. P., Jiang J. Eur. J. Inorg. Chem. 2004, 518-523.
https://doi.org/10.1002/ejic.200300510

38. Ercolani C. J. Porphyrins Phthalocyanines 2000, 4, 340-343.
https://doi.org/10.1002/(SICI)1099-1409(200006/07)4:4<340::AID-JPP242>3.0.CO;2-1

39. Afanasiev P., Sorokin A. B. Acc. Chem. Res. 2016, 49, 583-593.
https://doi.org/10.1021/acs.accounts.5b00458

40. Kroitor A.P., Cailler L.P., Martynov A.G., Gorbunova Y.G., Tsivadze A.Y., Sorokin A.B. Dalton Trans. 2017, 46, 15651-15655.
https://doi.org/10.1039/C7DT03703A

41. Bottomley L.A., Gorce J.N., Goedken V.L., Ercolani C. Inorg. Chem. 1985, 24, 3733-3737.
https://doi.org/10.1021/ic00217a008

42. Şahin Z., Meunier-Prest R., Dumoulin F., Işci Ü., Bouvet M. Inorg. Chem. 2020, 59, 1057-1067.
https://doi.org/10.1021/acs.inorgchem.9b02520

43. Kroitor A.P., Martynov A.G., Gorbunova Y.G., Tsivadze A.Y., Sorokin A.B. Eur. J. Inorg. Chem. 2019, 2019, 1923-1931.
https://doi.org/10.1002/ejic.201900029

44. Kienast A., Galich L., Murray K.S., Moubaraki B., Lazarev G., Cashion J.D., Homborg H. J. Porphyrins Phthalocyanines 1997, 1, 141-157.
https://doi.org/10.1002/(SICI)1099-1409(199704)1:2<141::AID-JPP18>3.3.CO;2-D

45. Markus R.T. The Measurement of Color. In: Color for Science, Art and Technology (Nassau K., Ed.), 1998. 490 p.
https://doi.org/10.1016/s1387-6783(98)80005-6

46. Mahy M., Van Eycken L., Oosterlinck A. Color Res. Appl. 1994, 19, 105-121.
https://doi.org/10.1111/j.1520-6378.1994.tb00070.x

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Unusual Cyan-Purple Electrochromism of Sandwich Phthalocyaninates Observed on the Example of µ-Carbido Diruthenium(IV) Complex

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