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ISSN 1998-9539

Bidentate Lactate Binding to La(III)-Cu(II) Metallacrown with L- Phenylalaninehydroximate Ligands: the Chiral Separation of L-Lactate

Marina A. Katkova,@ Evgeny V. Baranov, Galina S. Zabrodina, and Sergey Yu. Ketkov

G. A. Razuvaev Institute of Organometallic Chemistry of RAS, 603905 Nizhny Novgorod, Russia

@Corresponding author E-mail: marina@iomc.ras.ru

 
DOI: 10.6060/mhc200816k
 
The chiral La(III)-Cu(II) metallacrown bearing L-phenylalaninehydroximate ligands was probed for complexation towards racemic lactate. X-Ray diffraction analysis revealed the bidentate chelation of L-lactate in the solid state to form enantiopure crystals. L-Phenylalaninehydroximate La(III)-Cu(II) metallacrown showed, therefore, a strong preference for coordination of the L-type lactate providing the chiral separation of the target compound.