News

Impact Factor 2021 = 1.200 has been issued by ISI Web of Knowledge (JCR 2021).

SCImago Journal & Country Rank

ISSN 1998-9539

pH-Dependent Electrochemically Catalyzed Oxygen Reduction Behaviors of o-Substituted Co(III) Corroles

Wei Tang,a Yuanyuan Qiu,b Xiaonan Li,a@1 Rodah C. Soy,c John Mack,c@2 Tebello Nyokong,c and Xu Liangb@3
aDepartment of Children Health Care, Nanjing Children’s Hospital, Nanjing Medical University, 210008 Nanjing, PR China
bSchool of Chemistry and Chemical Engineering, Jiangsu University, 212013 Zhenjiang, PR China
cInstitute for Nanotechnology Innovation, Department of Chemistry, Rhodes University, 6140 Makhanda, South Africa
@1Corresponding author E-mail: xiaonan6189@163.com
@2Corresponding author E-mail: j.mack@ru.ac.za
@3Corresponding author E-mail: Liangxu@ujs.edu.cn
 
DOI: 10.6060/mhc200183l
Macroheterocycles 2020 13(2) 156-162
 
Herein, a series of three o-substituted Co(III) corroles with electron-donating/withdrawing moieties have been prepared and fully characterized. The different functional substituents at o-position of meso-phenyl rings results in tunable local environment, and unusual pH-dependent electrochemically catalyzed oxygen reduction behaviors were clearly observed.

References:

AttachmentSize
mhc200183l.pdf2.65 MB
mhc200183l_supp.pdf2.02 MB