Журнал "Макрогетероциклы"

Xu Xu,^a# Xinyi Dong,^b# Zhen Zhang,^b Xin Du,^a Weihua Zhu,^b,c Xu Liang,^b,c@1 Long Zhao,^b and Haijun Xu^a@2

^aJiangsu Co-innovation Center of Efficient Processing and Utilization of Forest Resources, College of Chemical Engineering, Jiangsu Key Lab of Biomass-based Green Fuels and Chemicals, Nanjing Forestry University, 210037 Nanjing, PR China

^bSchool of Chemistry and Chemical Engineering, Jiangsu University, 212013 Zhenjiang, PR China

^cState Key Laboratory of Coordination Chemistry, Nanjing University, 210000 Nanjing, PR China

^@1Corresponding author E-mail: liangxu@ujs.edu.cn

^@2Corresponding author E-mail: xuhaijun@njfu.edu.cn

^#These authors were contributed equally

DOI: 10.6060/mhc191176l

Macroheterocycles 2019 12(4) 403-408

Herein, the low symmetric 9,9’-(C₁₂H₂₅)₂-fluorene substituted corrole monomer and its bridged dimer are reported. The electronic structure investigation was carried out to confirm the electronic influence of 9,9’-(C₁₂H₂₅)₂-fluorene unit for corrole monomer and dimer. Solvent-dependent spectroscopic investigation explained the possible inner NH tautomerism.