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ISSN 1998-9539

Synthesis and Properties of 9,9’-(C12H25)2-Fluorene Substituted Corrole Monomer and its Bridged Dimer

Xu Xu,a# Xinyi Dong,b# Zhen Zhang,b Xin Du,a Weihua Zhu,b,c Xu Liang,b,c@1 Long Zhao,b and Haijun Xua@2

aJiangsu Co-innovation Center of Efficient Processing and Utilization of Forest Resources, College of Chemical Engineering, Jiangsu Key Lab of Biomass-based Green Fuels and Chemicals, Nanjing Forestry University, 210037 Nanjing, PR China

bSchool of Chemistry and Chemical Engineering, Jiangsu University, 212013 Zhenjiang, PR China

cState Key Laboratory of Coordination Chemistry, Nanjing University, 210000 Nanjing, PR China

@1Corresponding author E-mail:

@2Corresponding author E-mail:

#These authors were contributed equally


DOI: 10.6060/mhc191176l

Macroheterocycles 2019 12(4) 403-408


Herein, the low symmetric 9,9’-(C12H25)2-fluorene substituted corrole monomer and its bridged dimer are reported. The electronic structure investigation was carried out to confirm the electronic influence of 9,9’-(C12H25)2-fluorene unit for corrole monomer and dimer. Solvent-dependent spectroscopic investigation explained the possible inner NH tautomerism.

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