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ISSN 1998-9539

Chemical Transformations of the Vinyl Group in Natural Chlorins. The Synthesis of 3-Azidomethylchlorins

Marya E. Nikolaeva,a Alexander A. Popov,a Andrei V. Nechaev,a,b@ and Andrey F. Mironova

aLomonosov Institute of Fine Chemical Technologies, MIREA – Russian Technological University, 119571 Moscow, Russia

bFederal Scientific Research Centre “Crystallography and Photonics” of Russian Academy of Sciences, 119333 Moscow, Russia

@Corresponding author E-mail: chemorg@mail.ru

 

DOI: 10.6060/mhc190764n

Macroheterocycles 2019 12(4) 389-391

 

Transformation of 3-vinylchlorins into azidomethyl-derivatives was investigated for chlorin p6 trimethyl ester. The azide group allows modifying chlorophyll derivatives on pyrrole ring A by the use of “click reaction” with terminal alkynes. As an example, reaction with phenylacetylene was carried out.

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