Журнал "Макрогетероциклы"

Ufa Institute of Chemistry – Subdivision of the Ufa Federal Research Center of the Russian Academy of Sciences, 450054 Ufa, Russia

^@Corresponding author E-mail: mingaleevagalina@yandex.ru

 

DOI: 10.6060/mhc190661m

Macroheterocycles 2020 13(1) 79-82

 

The [1+1]-condensation reaction of natural castor oil (triglyceride of (R,Z)-(+)-12-hydroxy-9-octadecenoic acid) with malonic acid chloride was carried out by one-stage synthesis. Optically active macroheterocycles with four ester groups were obtained, their malonic fragment being additionally alkylated by 1-bromotridecane or 2-(8-bromooctyl)tetrahydro-2H-pyran.