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ISSN 1998-9539

Pseudomacrobicyclic Phthalocyaninate-Capped Cobalt(III) tris-Pyridineoximates: Template Synthesis, X-Ray Structure and Spectral Characteristics

Svetlana A. Belova (Savkina),a Semyon V. Dudkin,a@ Alexander S. Belov,a Yulia V. Nelyubina,a,b Valentin V. Novikov,a,c Yan V. Zubavichus,d and Yan Z. Voloshina,b

aNesmeyanov Institute of the Organoelement Compounds of the Russian Academy of Sciences, 119991 Moscow, Russia

bKurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, 119991 Moscow, Russia

cMoscow Institute of Physics and Technology, 141701 Dolgoprudny, Russia

dBoreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russia

@Corresponding author E-mail:


DOI: 10.6060/mhc190550d

Macroheterocycles 2019 12(2) 193-197


First pseudomacrobicyclic phthalocyaninate-capped cobalt(III) tris-pyridineoximates were obtained in moderate yields (40–49 %) by the direct template condensation of 2-acetylpyridineoxime with zirconium(IV) and hafnium(IV)phthalocyaninates on the cobalt ion as a matrix. These complexes were thoroughly characterized using elemental analysis, MALDI-TOF mass-spectrometry, NMR and UV-Vis spectroscopies and by the single-crystal X-ray diffraction. Their electrochemical behaviour was studied byusing the cyclic and differential pulse voltammetries.

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