Журнал "Макрогетероциклы"

Svetlana A. Belova (Savkina),^a Semyon V. Dudkin,^a@ Alexander S. Belov,^a Yulia V. Nelyubina,^a,b Valentin V. Novikov,^a,c Yan V. Zubavichus,^d and Yan Z. Voloshin^a,b

^aNesmeyanov Institute of the Organoelement Compounds of the Russian Academy of Sciences, 119991 Moscow, Russia

^bKurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, 119991 Moscow, Russia

^cMoscow Institute of Physics and Technology, 141701 Dolgoprudny, Russia

^dBoreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russia

^@Corresponding author E-mail: sdudkin@ineos.ac.ru

DOI: 10.6060/mhc190550d

Macroheterocycles 2019 12(2) 193-197

First pseudomacrobicyclic phthalocyaninate-capped cobalt(III) tris-pyridineoximates were obtained in moderate yields (40–49 %) by the direct template condensation of 2-acetylpyridineoxime with zirconium(IV) and hafnium(IV)phthalocyaninates on the cobalt ion as a matrix. These complexes were thoroughly characterized using elemental analysis, MALDI-TOF mass-spectrometry, NMR and UV-Vis spectroscopies and by the single-crystal X-ray diffraction. Their electrochemical behaviour was studied byusing the cyclic and differential pulse voltammetries.