Журнал "Макрогетероциклы"

Olga K. Grigorova,^a Alexei D. Averin,^a,b@ Olga A. Maloshitskaya,^a Franck Denat,^c and Irina P. Beletskaya^a,b

^aM.V. Lomonosov Moscow State University, Department of Chemistry, 119991 Moscow, Russia

^bA.N. Frumkin Institute of Physical Chemistry and Electrochemistry RAS, 119991 Moscow, Russia

^cInstitut de Chimie Moléculaire de l’Université de Bourgogne, Université de Bourgogne Franche-Comté, UMR CRNS n° 6302, BP 47870, Dijon 21078 CEDEX, France

^@Corresponding author E-mail: alexaveron@yandex.ru

DOI: 10.6060/mhc190337a

Macroheterocycles 2019 12(3) 312-318

Pd(0)-Сatalyzed amination of N,N’-di(bromobenzyl) substituted tetraazamacrocycles (cyclen, cyclam) with (S)-2,2’-diamino-1,1’-binaphthalene (BINAM) was employed for the synthesis of a novel type of chiral cryptands. Better yields were obtained for cyclen derivatives. The compounds were modified with dansyl groups to enhance their fluorescent properties. Cryptands theirselves and their dansyl derivatives were evaluated for sensing enantiomers of 7 amino alcohols and 21 metal cations.