Supramolecular Iron(III) Tetramesitylporphyrin Cluster Structure Assembled by Hydrogen Bonding with Sulfuric Acid

Evgeny V. Kudrik,^a,b Sergey E. Nefedov,^c@1 and Alexander B. Sorokin^a^@2

^aInstitut de Recherches sur la Catalyse et l’Environnement de Lyon (IRCELYON), 69626 Villeurbanne Cedex, France

^bInstitut of Macroheterocyclic Compounds, Ivanovo State University of Chemical Technology, 153000 Ivanovo, Russia

^cKurnakov Institute of General and Inorganic Chemistry, Russian Academy of Science, 119991 Moscow, Russia

^1@Corresponding author E-mail: snef@igic.ras.ru

^2@Corresponding author E-mail: alexander.sorokin@ircelyon.univ-lyon1.fr

DOI: 10.6060/mhc181004s

Macroheterocycles 2019 12(1) 29-34

We present here the first crystalline assembly of a supramolecular structure formed by iron(III) 5,10,15,20-tetrakis-
mesitylporphyrin via hydrogen bonding with charge compensating hydrosulfate residues. Two additional molecules of sulfuric acid provide hydrogen bonding connection of four iron porphyrin units to form a fragment with interporphyrin void where two iron sites are situated at 9.52 Å distance. The insertion of two molecules of sulfuric acid into cavity formed by four Fe(III) porphyrin molecules led to the formation of the cluster structure with dihedral angle of 53.3° between adjacent porphyrin molecules Fe(1A)N₄/Fe(2A)N₄ and parallel Fe(1A)N₄/Fe(1B)N₄ and Fe(2A)N₄/Fe(2B)N₄ planes. Such a supramolecular material, where four iron sites in the porphyrin ligand environment are strongly connected via network of the hydrogen bonds provides a new tool for exploring different applications involving multielectronic processes.

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Supramolecular Iron(III) Tetramesitylporphyrin Cluster Structure Assembled by Hydrogen Bonding with Sulfuric Acid

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