Журнал "Макрогетероциклы"

^aNesmeyanov Institute of Organoelement Compounds of  Russian Academy of Sciences, 119991 Moscow, Russia

^bKurnakov Institute of General and Inorganic Chemistry of  Russian Academy of Sciences, 119991 Moscow, Russia

^@Corresponding author E-mail: sdudkin@ineos.ac.ru

 

DOI: 10.6060/mhc181003d

Macroheterocycles 2018 11(4) 418-420

 

Earlier, the hybrid binuclear metallophthalocyaninate-capped iron and nickel(II) tris-pyridineoximates have been prepared using a two-step synthetic procedure via transmetalation reaction of their labile triethylantimony-capped precursors. We elaborated new efficient synthetic pathway to the preparation of the titled complexes. This synthetic approach is based on a one-pot template condensation of 2-acetylpyridinoxime with zirconium and hafnium(IV) phthalocyaninate on the corresponding metal ion(II) as a matrix, thus giving the target compounds in high yields (up to 83 %).