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ISSN 1998-9539

A Convenient Synthetic Route towards the Hybrid Binuclear Metallophthalocyaninato-Capped Iron and Nickel(II) Tris-pyridineoximates

Semyon V. Dudkin,a@ Svetlana A. Savkina,a Alexander S. Belov,a and Yan Z. Voloshina,b
aNesmeyanov Institute of Organoelement Compounds of  Russian Academy of Sciences, 119991 Moscow, Russia
bKurnakov Institute of General and Inorganic Chemistry of  Russian Academy of Sciences, 119991 Moscow, Russia
@Corresponding author E-mail:
DOI: 10.6060/mhc181003d
Macroheterocycles 2018 11(4) 418-420
Earlier, the hybrid binuclear metallophthalocyaninate-capped iron and nickel(II) tris-pyridineoximates have been prepared using a two-step synthetic procedure via transmetalation reaction of their labile triethylantimony-capped precursors. We elaborated new efficient synthetic pathway to the preparation of the titled complexes. This synthetic approach is based on a one-pot template condensation of 2-acetylpyridinoxime with zirconium and hafnium(IV) phthalocyaninate on the corresponding metal ion(II) as a matrix, thus giving the target compounds in high yields (up to 83 %).


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