Influence of Fluorosubstitution on the Structure of Zinc Phthalocyanine Thin Films

Darya D. Klyamer,^a,b Aleksandr S. Sukhikh,^a,b Sergey A. Gromilov,^a,b Vladimir N. Kruchinin,^c Evgeniy V. Spesivtsev,^c Aseel K. Hassan,^d and Tamara V. Basova^a,b@

^aNikolaev Institute of Inorganic Chemistry SB RAS, 630090 Novosibirsk, Russia

^bNovosibirsk State University, 630090 Novosibirsk, Russia

^cRzhanov Institute of Semiconductor Physics SB RAS, 630090 Novosibirsk, Russia

^dMaterials and Engineering Research Institute, Sheffield Hallam University, Sheffield, UK

^@Corresponding author E-mail: basova@niic.nsc.ru

DOI: 10.6060/mhc180794b
Macroheterocycles 2018 11(3) 304-311

In this work, thin films of tetrafluorosubstituted zinc phthalocyanine (ZnPcF₄) were deposited by organic molecular beam deposition and studied to reveal the effects of F-substituents on the ZnPcF₄ single crystals and thin films structure. A combination of spectral ellipsometry, atomic force microscopy and diffraction techniques has been used to elucidate the structural features and molecular orientation of thin films of ZnPcF₄. Structural features of the films grown by co-evaporation of ZnPc and ZnPcF₄(1:1) were also considered. Both ZnPcF₄ and ZnPc/ZnPcF₄ films have a preferred orientation along (001) plane with inclination angle of molecules relative to the substrate surface equal to 80° and the lower degree of crystallinity compared to the ZnPc film.

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Influence of Fluorosubstitution on the Structure of Zinc Phthalocyanine Thin Films

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