Effect of Anion on the C-Cl Bond Cleavage of Toxic Organochlorides Electrocatalyzed by Co(II) Porphyrin

Yuanyuan Qiu, He Luo, Minzhi Li, Junxia Wen, Weihua Zhu,^@1 Xifeng Zhang, and Xu Liang^@2

School of Chemistry and Chemical Engineering, Jiangsu University, 212013 Zhenjiang, China

^@1Corresponding author E-mail: sayman@ujs.edu.cn

^@2Corresponding author E-mail: liangxu@ujs.edu.cn

DOI: 10.6060/mhc180382z

Macroheterocycles 2018 11(3) 257-261

An electrochemically reduced Co(I) meso-tetraphenylporphyrin anion was examined in electron reductive dechlorination of environmental harmful organochlorides by using various supporting electrolytes. The tunable reactivities were formed when different supporting electrolytes were tested. For the first time the experimental and mechanistic investigations were combined, what provided useful information for future rational molecular design towards highly efficient removal of environmental harmful organochloride catalyzed by metalloporphyrins.

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Effect of Anion on the C-Cl Bond Cleavage of Toxic Organochlorides Electrocatalyzed by Co(II) Porphyrin

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