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ISSN 1998-9539

Coordination Compounds Based on Metacyclophane Derivatives

A. S. Ovsyannikov,a,c@1 S. Ferlay,b@2 E. F. Chernova,b,c S. E. Solovieva,a,c@3 I. S. Antipin,a,c and M. W. Hosseinib@4
Dedicated  to Academician Aslan Yu. Tsivadze on the occasion of his 75th Anniversary
aA.E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, 420088 Kazan, Russian Federation
bMolecular Tectonics Laboratory, Université de Strasbourg, CNRS, CMC UMR 7140, F-67000 Strasbourg, France
cKazan Federal University, 420008 Kazan, Russian Federation
@3E-mail: svsol@iopc.ru
 
DOI: 10.6060/mhc171256o
Macroheterocycles 2017 10(4-5) 410-420
 
The solid-state structures of coordination complexes or extended coordination polymers based on the macrocyclic [1.1.1.1]metacyclophane backbone that inherently possesses a blocked 1,3-alternate conformation, have been reviewed. In order to obtain new ligands, N donor coordinating groups like cyano, pyridine, imidazole or pyrazole have been appended to the di or tetrasubstituted macrocycle platform.  When combined with transition metals, metallamacrocycles or coordination networks of diverse dimensionalities have been obtained.. 

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